化学学报 ›› 1965, Vol. 31 ›› Issue (3): 222-228. 上一篇    下一篇

论文

中国乌头之研究——Ⅵ.雪上一枝蒿的生物碱(2)

朱任宏, 方聖鼎   

  1. 中国科学院药物研究所
  • 收稿日期:1964-07-03 出版日期:1965-06-15 发布日期:2013-06-03

THE ALKALOIDS OF THE CHINESE DRUG, ACONITUM SPP. Ⅵ. ALKALOIDS FROM HYE-SHANG-YI-ZHI-HAO, ACONITUM BULLATIFOLIUM LÉVL. VAR. HOMOTRICHUM W. T. WANG. (2)

CHU JEN-HUNG, FANG SHENG-DIN   

  1. Institute of Materia Medica, Academia Sinica
  • Received:1964-07-03 Online:1965-06-15 Published:2013-06-03

从云南省昭通县产的雪上一枝蒿中共分得生物碱五种,其中三种为已知物,即烏头碱、次岛头碱和一枝蒿乙素,另二种为新生物碱,暂名为一枝蒿戊素和己素。一枝蒿戊素的分子式为C24H39O6N,其示性式为C19H22(OH)3(OCH3)3-(N·C2H5);一枝蒿己素的分子式为C24H39O7N,其示性式为C19H21(OH)4(OCH3)3(N·C2H5);另从云南省东川县出产的雪上一枝蒿中,尚分得一新生物碱,暂称为一枝蒿庚素,分子式为C21H31O3N,其示性式为C19H24(:O)(OH)2(N·C2H5)。

In a previous communication,the authors have reported the isolation of four new alkaloids from the Chinese drug,Hye-shang-yi-zhi-hao (Aconitum bullatifolium Lévl.var.homotrichum W.T.Wang.),provisionally named bullatine A,B,C,and D.This paper reports the isolation of five alkaloids from the same plant,collected from different districts of Yunnan.Three of them are identified as aconitine,hypaconitine,and bullatine B.The other two appear to be new alkaloids,and are named bullatine E and F.