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化学学报
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化学学报 ›› 1965, Vol. 31 ›› Issue (4): 304-307. 上一篇    下一篇

论文

甾体化合物XLV.新法合成16α,17α-異丙叉二氧基黄体酮

黄鳴龙, 龐卿輝   

  1. 中国科学院有机化学研究所
  • 投稿日期:1964-07-22 发布日期:2013-06-03

A NEW SYNTHESIS OF 16α, 17α-ISOPROPYLIDENEDIOXYPROGESTERONE

HUANG MINLON, PANG CHIN-HWI   

  1. Institute of Organic Chemistry, Academia Sinica
  • Received:1964-07-22 Published:2013-06-03

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272

被引次数

3

应用从化合物(Ⅱ)易得的16α-羟基化合物(Ⅲ)或其乙酸酯(Ⅳ)作原料,经羟基化(Ⅴ),丙酮缩合物的形成(Ⅶ)及氧化(Ⅷ及Ⅸ)等四步,即得目的物Ⅸ。

The title compound (Ⅸ) has been synthesized with 16α-hydroxy compound (Ⅲ) or its diacetate (Ⅳ) as the starting material in four steps, namely through hydroxylation (Ⅴ),acetonide formation (Ⅶ),and oxidations (Ⅷ, Ⅸ).