化学学报 ›› 1982, Vol. 40 ›› Issue (12): 1123-1128. 上一篇    下一篇

论文

吐鲁番风化煤黄腐酸的结构研究Ⅱ.

张德和, 刘登良, 张文信, 王光辉   

  1. 中国科学院化学研究所 北京
  • 投稿日期:1981-11-09 发布日期:2013-06-03
  • 通讯作者: 张德和

STUDY ON THE STRUCTURE OF FULVIC ACID FROM WEATHERED COAL OF TULUFAN Ⅱ.

ZHANG DE-HE, LIU DENG-LIANG, ZHANG WEN-XIN, WANG GUANG-HUI   

  1. Institute of Chemistry Academia Sinica, Beijing
  • Received:1981-11-09 Published:2013-06-03

吐鲁番风化煤黄腐酸经CH2N2甲基化和分级后,取其大分子量级分G6~G12(Mn=663~6601)用KMnO4氧化降解.降解物再经甲基化后用GC分离成24个组分.经Gc/MS分析结果与标准化合物对照,确定其中17种组分和同一黄腐酸样品中的小分子量级分所含的化合物相同,此外还有1,2,3一苯三甲酸、1,2,3,4—苯四甲酸、间苯二甲酸、对苯二甲酸及少量n-C18H38,C19H36和10-甲基十九酸.与其它来源的黄腐酸和黑腐酸不同,吐鲁番黄腐酸具有极为明显的芳香结构特征.

Fulvia acid extracted from weathered coal (Tnlnfan, Xinjiang) was methylated with CH2N2 and was then fractionated.The higher molecular weight fractions G6-G12(M-663-6601) were oxidatively degraded.with KMnO4, The degradation products thus obtained were again methylatsd and were then separated into 24 components by G0, 17 of which were identified as the same compounds which had been separated from the low molecular weight fractions as reported previously.The other identified compounds are 1, 2, 3-benzene-trioarboxylic acid, 1, 2, 3, 4-benzene-tetraoarbogylio acid, isophthalia acid, terephthalio said, as well as a small amount of n-G18H38, G19H38 and 10-methyl-nonadecanoio acid.Differing from fulvio and humio acids from other origins, the fulvia acid now studied.has very remarkable aromatic struatural characteristics.