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化学学报
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化学学报 ›› 1987, Vol. 45 ›› Issue (2): 145-149. 上一篇    下一篇

研究论文

黄花棘豆化学成分的研究II:两种三萜皂苷的结构

孙荣奇;程东亮;贾忠建;朱子清   

  1. 兰州大学化学系
  • 发布日期:1987-02-15

Studies on the chemical components of oxytropis ochrocephala Bunge II: The structures to two triterpenoid saponins

SUN RONGQI;CHENG DONGLIANG;JIA ZHONGJIAN;ZHU ZIQING   

  • Published:1987-02-15

PDF

667

被引次数

50

从黄花棘豆的总皂苷中分离出两个新皂苷1和2.经光谱分析及化学方法确证,1为3-O-[α-L-鼠李吡喃糖基(1→2)-β-D-葡萄吡喃糖基(1→4)-β-D-葡萄吡喃糖醛酸基]-黄豆醇B;2为3-O-[α-L-鼠李吡喃糖基(1→2)-α-L-阿拉伯吡喃糖基(1→4)-β-D-葡萄吡喃糖醛酸基]-黄豆醇B.

关键词: 化学成分, 皂角苷, 吡喃糖, 葡萄糖, 光谱分析, 糖苷, 三萜, 鼠李糖, 阿拉伯糖, 豆科

Two new triterpenoid saponins were isolated from the total saponin mixture of O. ochrocephala. The structures were elucidated as 3-O-[a-L-rhamnopyranosyl(1?)-b-D-glucopyranosyl(1?)-b-D-glucuron opyranosyl]-soyasapogenol B and 3-O-[a-L-rhamnopyranosyl(1?)-a-L-arabinopyranosyl(1?)-b-D-glucur onopyranosyl]-soyasapogenol B by spectral anal. and chem. transformations.

Key words: CHEMICAL COMPOSITION, SAPONINS, PYRANOSE, GLUCOSE, SPECTROGRAPHIC ANALYSIS, GLYCOSIDE, TRITERPENE, RHAMNOSE, ARABINOSE, LEGUMINOSAE

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