化学学报 ›› 1992, Vol. 50 ›› Issue (9): 874-876. 上一篇    下一篇

研究论文

卟啉镍分子的激发态和反饱和吸收

封继康;高旭岭;费浩生;孙家钟   

  1. 吉林大学化学系
  • 发布日期:1992-09-15

The excited states and reverse saturable absorption of ni-porphyrin molecule

FENG JIKANG;GAO XULING;FEI HAOSHENG;SUN JIAZHONG   

  • Published:1992-09-15

用INDO/CI方法研究了卟啉镍分子的电子结构、紫外光谱、激发态,并从理论上指出卟啉镍分子存在反饱和吸收的微观机制.

关键词: 紫外分光光度法, 激发态, 电子结构, 卟啉, 微分重叠间忽略近似, 反饱和吸收, 卟啉镍

The INDO/CI method was used to study the electronic structure, UV spectrum, and excited states of Ni-porphyrin; a micromechanism of reverse saturable absorption of Ni-porphyrin mol. is suggested.

Key words: ULTRAVIOLET SPECTROPHOTOMETRY, EXCITED STATE, ELECTRONIC STRUCTURE, PORPHYRIN, INTERMEDIATE NEGLECT OF DIFFERENTIAL OVERLAP APPROXIMATION (IND

中图分类号: