化学学报 ›› 1995, Vol. 53 ›› Issue (11): 1041-1046.    下一篇

研究论文

热环合反应速率的量子理论

许宗荣;田之悦   

  1. 成都科学技术大学原子分子科学所
  • 发布日期:1995-11-15

The quantum theory of reactive rate for ring formation thermoreaction

XU ZONGRONG;TIAN ZHIYUE   

  • Published:1995-11-15

应用多声子无辐射跃迁理论研究热环合反应, 给出热环合反应速率的一般公式。在高温条件下得出反应速率和活化能公式。所得公式可适用于多个环合点的热环合反应。

关键词: 活化能, 反应速度, 热环合反应, 量子理论

Using the multiphonon non-radiative transition theory to investigate the ring formation thermoreaction, the formula of the reactive rate for the ring formation thermoreaction has been derived. In the high-temperature limitation, the reactive rate and the activation energy has been given. These formulae derived can be used to the ring formation with multi-points ring formation reactions.

Key words: ACTIVATION ENERGY, REACTION RATE, QUANTUM THEORY

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