化学学报 ›› 1997, Vol. 55 ›› Issue (11): 1108-1115. 上一篇    下一篇

研究论文

微盘电极上计时电流的数值模拟及其验证

钱卫军;金葆康;史汉生;于俊生;张祖训   

  1. 南京大学化学系
  • 发布日期:1997-11-15

Digital simulation of chronoamperometric current at microdisk electrode and its verification

QIAN WEIJUN;JIN BAOKANG;SHI HANSHENG;YU ZUNSHENG;ZHANG ZUXUN   

  • Published:1997-11-15

本文引入了一种适用于二维电化学扩散问题研究的新的数值模拟方法[有限分析(FA)法], 并对微盘电极上的二维扩散问题进行了研究。模拟了微盘电极上的可逆及准可逆过程的计时电流, 并进行了实验验证, 实验与模拟结果很好地相符。

关键词: 氯化钾, 亚铁氰化钾, 微电极, 数值模拟, 有限元分析, 电化学扩散

A new numerical simulation method---finite analytic (FA) method was introduced in this paper. The two-dimensional diffusion problems at microdisk electrode were studied and the reversible and quasi-reversible chronoamperometric responses were simulated. The experiments of reversible chronoamperomtry were carried out and the experimental results were in good agreement with the simulated ones.

Key words: POTASSIUM CHLORIDE, POTASSIUM FERROCYANIDE, MICROELECTRODE, NUMERICAL SIMULATION, FINITE ELEMENT ANALYSIS

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