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化学学报
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化学学报 ›› 1989, Vol. 47 ›› Issue (3): 276-278. 上一篇    下一篇

研究论文

[Ba(18-冠-6)(H2O)(OH)][Fe(NCS)4]的分子和晶体结构

樊悦明;杜高英;张文兴   

  1. 山东大学化学系
  • 发布日期:1989-03-15

The molecular and crystalline structure of [Ba(18-crown-6)(H2O(OH)][Fe(NCS)4]

FAN YUEMING;DU GAOYING;ZHANG WENXING   

  • Published:1989-03-15

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524

被引次数

3

本文用凝胶法培养出18-冠-6钡和硫氰酸铁的配合物单晶, 并用X射线衍射分析了其晶体和分子结构.

关键词: 晶体结构, 分子结构, Ｘ射线衍射分析, 冠式化合物, 硫氰酸盐, 铁络合物, 过渡金属络合物, 凝胶作用, 钡络合物

The title compound by prepared and analyzed by x-ray diffractometry. It is orthorhombic, space group Pcmn, with a 12.191(3), b 14.619(2), c 16.488(4) ? dc = 1.638 for Z = 4; R = 0.045 and Rw = 0.053. Ba(II) is coordinated to 18-crown-6, OH-, and H2O; forming a distorted octahedral.

Key words: CRYSTAL STRUCTURE, MOLECULAR STRUCTURE, X-RAY DIFFRACTION ANALYSIS, CROWN ETHER COMPOUNDS, THIOCYANATE, IRON COMPLEX, TRANSITION METAL COMPLEX, GELATION, BARIUM COMPLEX

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