化学学报 ›› 1964, Vol. 30 ›› Issue (6): 557-561. 上一篇    下一篇

论文

用磷酸三丁酯萃取分光光度法测定微量碲

张佩樺   

  1. 地质部华东地质科学研究所中心实验室
  • 投稿日期:1963-12-07 发布日期:2013-06-03

SPECTROPHOTOMETRIC DETERMINATION OF TRACES OF TELLURIUM AFTER EXTRACTION WITH TBP

CHANG PEI-HUA   

  1. The Central Laboratory, Institute of Geological Science of East-China, Ministry of Geology
  • Received:1963-12-07 Published:2013-06-03

在氢溴酸溶液中,加抗坏血酸还原游离溴后,用TBP萃取黄色溴化碲络合物,使碲与其他干扰元素分离,而直接比色测定碲.实验结果表明黄色络合物在TBP甲苯溶液中最大吸收在450毫微米,溶液颜色稳定,并符合Beer定律.用20%TBP甲苯溶液萃取即能使萃取液消光度达最高值.溴化钠可代替部分氢溴酸.萃取率和分配系数分别为95.6%和21.7.微量铁、毫克量铜、强氧化剂和强还原剂干扰,而其他包括常与碲在矿石中共生的硒、金、银、汞、铊等元素及一些常见的酸及盐类均无显著影响.

In the hydrobromic acid solution,tellurium(Ⅳ) forms a yellow bromide complex which can be extracted by tributyl phosphate(TBP).The addition of ascorbic acid to the aqueous solution serves to remove some interferences.Experiments show that the maximum absorption of the yellow complex is at 450 m,u.Its solution is stable and obeys Beer's law.TBP may be diluted by toluene.Extinction reaches maximum,when extraction is made with 20% TBP in toluene.The extractability of tellurium complex by TBP depends on the concentration of the bromide ions in the aqueous solution.In the absence of sodium bromide,extinction will not reach maximum,when the hydrobromic acid concentration is below 4.2 N.