二维疏水铜基纳米片的合成及在硫醚类化合物催化氧化中的应用

doi:10.6023/A20050165

化学学报 ›› 2020, Vol. 78 ›› Issue (9): 980-988.DOI: 10.6023/A20050165 上一篇下一篇

研究论文

二维疏水铜基纳米片的合成及在硫醚类化合物催化氧化中的应用

杨忠杰^a,b, 张小飞^a, 施亚男^a,b, 隆昶^c, 张彬灏^a,d, 闫书豪^a,d, 常琳^a,b, 唐智勇^a,b

a 国家纳米科学中心中国科学院纳米系统与多级次制造重点实验室北京 100190;
b 中国科学院大学纳米科学与技术学院北京 100049;
c 哈尔滨工业大学材料学院哈尔滨 150001;
d 中国科学院大学中丹学院北京 100049

投稿日期:2020-05-12 发布日期:2020-07-10
通讯作者: 唐智勇 E-mail:zytang@nanoctr.cn
基金资助:
项目受中国科学院战略重点研究计划（No.XDB36000000）、国家重点基础研究计划（No.2016YFA0200700）、国家自然科学基金（Nos.21890381，21721002）、中国科学院前沿科学重点项目（No.QYZDJ-SSW-SLH038）和王宽诚教育基金会资助.

Synthesis of Two-dimensional Hydrophobic Copper-based Nanosheets and Their Application in Catalytic Oxidation of Sulfides

Yang Zhongjie^a,b, Zhang Xiaofei^a, Shi Yanan^a,b, Long Chang^c, Zhang Binhao^a,d, Yan Shuhao^a,d, Chang Lin^a,b, Tang Zhiyong^a,b

a CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China;
b School of Nanoscience and Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
c School of Materials Science and Engineering, Harbin Institute of Technology, Harbin 150080, China;
d Sino-Danish Center for Education and Research, Sino-Danish College, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2020-05-12 Published:2020-07-10
Supported by:
Project supported by the Strategic Priority Research Program of Chinese Academy of Sciences (No. XDB36000000), National Key Basic Research Program of China (No. 2016YFA0200700), National Natural Science Foundation of China (Nos. 21890381, 21721002), Frontier Science Key Project of Chinese Academy of Sciences (No. QYZDJ-SSW-SLH038), and K.C.Wong Education Foundation.

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摘要/Abstract

二维纳米材料因其具有独特的物理化学性质得到了广泛的研究与关注.然而，自下而上制备稳定的二维纳米材料仍然面临巨大挑战.本工作以1，4-苯二硫醇为有机配体和Cu⁺为金属前驱体，通过配位相互作用自组装构筑了一种新型的二维金属有机配合物纳米片（Cu-BDT）.Cu-BDT纳米片的形貌和结构被多种技术详细表征，包括粉末X射线衍射（P-XRD）、傅里叶变换红外光谱（FT-IR）、激光拉曼光谱（Raman）、扫描电子显微镜（SEM）、透射电子显微镜（TEM）、原子力显微镜（AFM）、X射线光电子能谱（XPS）、电感耦合等离子体发射光谱仪（ICP-OES）和接触角测试.催化实验证实，Cu-BDT纳米片表面暴露充分的活性位点和疏水特性有利于硫醚类化合物氧化反应的进行，可高效转化为亚砜类产物.

关键词: 金属有机配合物, 二维纳米片, 疏水性, 硫醚类化合物氧化

Two-dimensional nanomaterials have received extensive attention because of their unique physicochemical properties. However, bottom-up synthesis of two-dimensional (2D) stable nanomaterials still remains great challenge. In this work, a novel 2D metal-organic (Cu-BDT) nanosheet is constructed at room temperature by coordinative self-assembly, namely, using monovalent copper ion as the metal precursor and 1,4-benzenedithiol as organic ligand. As-synthesized Cu-BDT nanosheets are fully characterized by various techniques including powder-diffraction of X-rays (P-XRD), Fourier transform infrared spectrometer (FT-IR), Raman spectra (Raman), scanning electron microscopy (SEM), transmission electron microscope (TEM), atomic force microscope (AFM), X-ray photoelectron spectroscopy (XPS), inductively coupled plasma optical emission spectrometer (ICP-OES) and contact angle test. The catalytic result verifies that the Cu-BDT nanosheet surfaces possess abundant active sites and good hydrophobicity, which facilitate oxidation of sulfides into sulfoxide compounds.

Key words: metal organic coordination complex, two-dimensional nanosheet, hydrophobicity, sulfides oxidation

引用此文

杨忠杰, 张小飞, 施亚男, 隆昶, 张彬灏, 闫书豪, 常琳, 唐智勇. 二维疏水铜基纳米片的合成及在硫醚类化合物催化氧化中的应用[J]. 化学学报, 2020, 78(9): 980-988.

Yang Zhongjie, Zhang Xiaofei, Shi Yanan, Long Chang, Zhang Binhao, Yan Shuhao, Chang Lin, Tang Zhiyong. Synthesis of Two-dimensional Hydrophobic Copper-based Nanosheets and Their Application in Catalytic Oxidation of Sulfides[J]. Acta Chimica Sinica, 2020, 78(9): 980-988.

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二维疏水铜基纳米片的合成及在硫醚类化合物催化氧化中的应用

Synthesis of Two-dimensional Hydrophobic Copper-based Nanosheets and Their Application in Catalytic Oxidation of Sulfides

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