Synthesis, Crystal Structure and Thermal Analysis of Two New Energetic Compounds (AIM)NO3 and (AIM)(HTNR)稨2O

doi:10.6023/A1106081

Acta Chimica Sinica ›› 2012, Vol. 0 ›› Issue (04): 471-478.DOI: 10.6023/A1106081 Previous Articles Next Articles

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含能化合物(AIM)NO₃ 与(AIM)(HTNR)·H₂O 的合成、晶体结构及性质研究

汤崭, 杨利, 乔小晶, 张同来, 张建国, 梁彦会

爆炸科学与技术国家重点实验室北京理工大学北京 100081

投稿日期:2011-06-08 修回日期:2011-09-08 发布日期:2011-11-01
通讯作者: 杨利
基金资助:
爆炸科学与技术国家重点实验室(北京理工大学)重点基金(Nos. ZDKT10-01b, ZDKT08-01); 教育部新世纪优秀人才计划(No. NCET-09-0051)资助项目.

Synthesis, Crystal Structure and Thermal Analysis of Two New Energetic Compounds (AIM)NO₃ and (AIM)(HTNR)稨₂O

Tang Zhan, Yang Li, Qiao Xiaojing, Zhang Tonglai, Zhang Jianguo, Liang Yanhui

State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081

Received:2011-06-08 Revised:2011-09-08 Published:2011-11-01
Supported by:
Project supported by the Foundation of State Key Laboratory of Explosion Science and Technology (Beijing Institute of Technology) of China (No. ZDKT10-01b, ZDKT08-01), Program for New Century Excellent Talents in University (No. NCET-10-0051).

Two new energetic compounds (AIM)NO₃ and (AIM)(HTNR)·H₂O have been prepared directly by reacting 2-azidoimidazolium with HNO₃ and 2,4,6-trinitroresorcinol (TNR). Single crystals suitable for X-ray measurement were obtained. The compounds were characterized by elemental analysis, fourier transform infrared (FTIR) spectra, single crystal X-ray diffraction, differential scanning calorimetry (DSC), and thermogravimetry-differential thermogravimetry (TG-DTG) analysis. (AIM)NO₃ belongs to a monoclinic system with P2₁/c space group and cell parameters of a＝17.034(3) Å, b＝6.5214(13) Å, c＝13.095(3) Å, β＝111.78(3)°, V＝1350.8(5) nm³; D_c＝1.693 g/cm³. The compound is formed by AIM⁺ and NO₃^-, and belongs to an ionic compound. There are a lot of intramolecular and intermolecular hydrogen bonds existing in the compound, which makes the compound more stable. (AIM)(HTNR)·H₂O belongs to a triclinic system with P1 space group and cell parameters of a＝6.4900(13) Å, b＝7.4286(15) Å, c＝15.401(3) Å, α＝101.57(3)°, β＝98.56(3)°, γ＝99.89(3)°, V＝703.6(2) Å³; D_c＝1.757 g/cm³. The compound is formed by AIM⁺ and HTNR^-, and belongs to an ionic compound. Under nitrogen atmosphere with a heating rate of 10 ℃/min, the thermal decomposition of the title compounds show that there is only one exothermic process with released gas, respectively. Sensitivities of the title compounds have been studied and the result show that (AIM)NO₃ has good flame sensitivity.

Key words: 2-azidoimidazolium, nitric acid, 2,4,6-trinitroresorcinol (TNR), crystal structure, thermal analysis, sensitivity

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Tang Zhan, Yang Li, Qiao Xiaojing, Zhang Tonglai, Zhang Jianguo, Liang Yanhui. Synthesis, Crystal Structure and Thermal Analysis of Two New Energetic Compounds (AIM)NO₃ and (AIM)(HTNR)稨₂O[J]. Acta Chimica Sinica, 2012, 0(04): 471-478.

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含能化合物(AIM)NO₃ 与(AIM)(HTNR)·H₂O 的合成、晶体结构及性质研究

Synthesis, Crystal Structure and Thermal Analysis of Two New Energetic Compounds (AIM)NO₃ and (AIM)(HTNR)稨₂O

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含能化合物(AIM)NO3 与(AIM)(HTNR)·H2O 的合成、晶体结构及性质研究