Acta Chimica Sinica ›› 2012, Vol. 0 ›› Issue (04): 441-444.DOI: 10.6023/A1106183 Previous Articles     Next Articles

Full Papers


高丽华a, 张金凤a, 孙庆玲a, 王科志b   

  1. a 北京工商大学理学院化学系 北京 100048;
    b 北京师范大学化学学院 北京 100875
  • 投稿日期:2011-06-18 修回日期:2011-08-22 发布日期:2011-10-25
  • 通讯作者: 高丽华
  • 基金资助:

    国家自然科学基金(Nos. 20871011, 90922004)、北京市自然科学基金(No. 2092011)和北京工商大学研究生科学创新基金资助项目.

Preparation and Photoelectric Conversion of Dipolar Hemicyanine Dye/Polyoxometalate Self-Assembled Films

Gao Lihuaa, Zhang Jinfenga, Sun Qinglinga, Wang Kezhib   

  1. a Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048;
    b College of Chemistry, Beijing Normal University, Beijing 100875
  • Received:2011-06-18 Revised:2011-08-22 Published:2011-10-25
  • Supported by:

    Supported by the National Natural Science Foundation of China (Nos. 20871011, 90922004), Beijing Municipal Natural Science Foundation (No. 2092011), and Scientific Research Foundation of Graduate School of Beijing Technology and Business University.

A new inorganic-organic hybrid self-assembled film was prepared by alternative adsorption of polyoxometalate (K10P2W18Cd4(H2O)2O68) and dipolar hemicyanine dye (H6) and studied by UV-Vis spectroscopy and photoelectrochemistry. The film was uniformly deposited with controllable layer number, red-shifted visible absorption band, and stable and large photoelectric signal. The effects of bias voltages, electron donor and electron acceptor on the photocurrent generation were discussed.

Key words: hemicyanine, polyoxometalate, self-assembled film, UV-Vis spectroscopy, photoelectric conversion