Synthesis and Characterization of Hexagonal Boron Carbonitride Compounds Prepared by Solvothermal Method

doi:10.6023/A1012212

Acta Chimica Sinica ›› 2012, Vol. 0 ›› Issue (04): 436-440.DOI: 10.6023/A1012212 Previous Articles Next Articles

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六方硼碳氮化合物的溶剂热合成与表征

周友, 高发明, 郭文锋, 侯莉

燕山大学环境与化学工程学院秦皇岛 066004

投稿日期:2010-12-21 修回日期:2011-09-26 发布日期:2011-11-01
通讯作者: 高发明
基金资助:
国家自然科学基金(No. 21071122)和教育部博士学科点专项基金(No. 20091333110009)和河北省杰出青年基金(No. E2010001169)资助项目.

Synthesis and Characterization of Hexagonal Boron Carbonitride Compounds Prepared by Solvothermal Method

Zhou You, Gao Faming, Guo Wenfeng, Hou Li

College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004

Received:2010-12-21 Revised:2011-09-26 Published:2011-11-01
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21071122) and Research Fund for the Doctoral Program of Higher Education of China ( No. 20091333110009) and the Outstanding Youth Fund of Hebei Province (No. E2010001169).

A solvothermal method has successfully applied to prepare hexagonal boron carbonitride from CH₃CN, NaN₃ and NaBF₄ in benzene at 400 ℃. The synthesized product was characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), select area electron diffraction (SAED), X-ray energy-dispersive spectroscopy (EDS), and electron energy loss spectroscopy (EELS). XRD and SAED indicated that the synthesized product are h-BCN with the lattice constants of a＝0.2678 nm and c＝0.6639 nm. TEM images reveal that the products mainly consist of nanorods and quartet prism-like nanostructure. The results of EELS and EDS suggested that the product was composed of elements of B, C and N, and the chemical formula was B_0.23C_0.60N_0.17. FTIR exhibited that the product had C—N, B—C and B—N bonds, indicating that an atomic-level hybrid of the three elements was synthesized.

Key words: boron carbonitride, solvothermal synthesis, transmission electron microscopy

Cite this article

Zhou You, Gao Faming, Guo Wenfeng, Hou Li. Synthesis and Characterization of Hexagonal Boron Carbonitride Compounds Prepared by Solvothermal Method[J]. Acta Chimica Sinica, 2012, 0(04): 436-440.

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六方硼碳氮化合物的溶剂热合成与表征

Synthesis and Characterization of Hexagonal Boron Carbonitride Compounds Prepared by Solvothermal Method

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