Synthesis of Polyallene-Based ABA Triblock Copolymer

doi:10.6023/A1107151

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (24): 2987-2994.DOI: 10.6023/A1107151 Previous Articles Next Articles

Full Papers

含聚联烯的三嵌段共聚物的合成

吕绪良*^,1, 贾其¹, 荣先辉², 唐厚超¹, 吴超¹

(¹解放军理工大学工程兵工程学院南京 210007)
(²解放军理工大学科研部南京 210007)

投稿日期:2011-07-15 修回日期:2011-08-01 发布日期:2011-08-08
通讯作者: 吕绪良 E-mail:xllu1957@126.com

Synthesis of Polyallene-Based ABA Triblock Copolymer

Lü Xuliang*^,1; Jia Qi¹; Rong Xianhui²; Tang Houchao¹; Wu Chao¹

(¹Engineering Institute of Corps of Engineer, PLA University of Science and Technology, Nanjing 210007)
(² Research and Development Section, PLA University of Science and Technology, Nanjing 210007)

Received:2011-07-15 Revised:2011-08-01 Published:2011-08-08

Polyallene has some particular application due to its unique structure, but study on copolymer containing polyallene was limited because of its polymerization methods. We first prepared Azo-TEMPO (2,2,6,6-tetramethyl-1-piperidine-N-oxyl) bifunctional initiator. Next, PS-b-PPOA-b-PS [Polystyrene-b-poly (phenoxyallene)-b-polystyrene] was prepared by sequential radical polymerization of phenoxyallene (POA) and NMRP (nitroxide-mediated radical polymerization) of styrene. Polyallene-based copolymer was easily prepared by the mechanism transfer strategy, which greatly expands its application.

Key words: polyallene, block copolymer, bifunctional initiator

Cite this article

LV Xu-Liang, JIA Qi, RONG Xian-Hui, TANG Hou-Chao, WU Chao. Synthesis of Polyallene-Based ABA Triblock Copolymer[J]. Acta Chimica Sinica, 2011, 69(24): 2987-2994.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Weihua Li. “Bridge” Makes Differences to the Self-assembly of Block Copolymers [J]. Acta Chimica Sinica, 2021, 79(2): 133-138.
[2]	Li Rongye, Khiman Mehul, Sheng Li, Sun Jing. pH/Solvent Tunable Hierarchical Nanostructures Assembled from an Amphiphilic Polypeptide-containing Triblock Copolymer [J]. Acta Chimica Sinica, 2020, 78(11): 1235-1239.
[3]	Cui Huina, Qiu Feng, Peng Juan. Synthesis and Properties of an All-Conjugated Polythio-phene-Polyselenophene Diblock Copolymer [J]. Acta Chim. Sinica, 2018, 76(9): 691-700.
[4]	Liu Ming, Yang Yingzi, Qiu Feng. A Strong Segregation Theory for Ring Block Copolymers [J]. Acta Chim. Sinica, 2017, 75(9): 884-892.
[5]	Ding Yanchun, Yu Yanlei, Wei Jia. Synthesis and Self-assembly Behavior of Photo-responsive Diblock Copolymers with Different Hydrophilic/Hydrophobic Ratios [J]. Acta Chimica Sinica, 2014, 72(5): 602-608.
[6]	Xia Binkai, Li Weihua, Qiu Feng. Self-assembling Behaviors of Symmetric Diblock Copolymers in C Homopolymers [J]. Acta Chimica Sinica, 2014, 72(1): 30-34.
[7]	Zhang Guangmeng, Yang Jiping, Chen Gong. Self-assembly of Tetraaniline-PEG-Tetraaniline Block Copolymer Thin Films [J]. Acta Chimica Sinica, 2014, 72(1): 83-88.
[8]	Wang Ruijuan, Wang Yilin. Interaction of Anionic Sulfonate Gemini Surfactant with PEO-PPO-PEO Triblock Copolymers [J]. Acta Chimica Sinica, 2014, 72(1): 41-50.
[9]	Yang Hui, Peng Juan, Qiu Feng. The Influencing Factors on the Ring-shaped Morphology in PI-b-P2VP Diblock Copolymer [J]. Acta Chimica Sinica, 2013, 71(08): 1141-1148.
[10]	Pan Gaoxiang, Feng Ze, Wei Jia, Yu Yanlei. Synthesis and Self-assembly Behavior of a Thermo-/photo-dual Responsive Triblock Copolymer [J]. Acta Chimica Sinica, 2013, 71(05): 733-738.
[11]	Hu Fangzhen, Chen Shengdian, Li Hui, Sun Jingjing, Sheng Ruilong, Luo Ting, Cao Amin. Preparation of New Amphiphilic Liquid-Crystal Diblock Copolymers Bearing Side-on Cholesteryl Mesogen and Their Self-aggregation [J]. Acta Chimica Sinica, 2013, 71(03): 351-359.
[12]	Ma Yuhong, Zhang Bing, Zhao Changwen, Liu Lianying, Jiang Shan, Liang Shujun, Yang Wantai. A Novel Macroinitiator Based on the Copolymer of α-Methylstyrene Synthesis and Its Application in Preparing Block and Graft Polymers [J]. Acta Chimica Sinica, 2013, 71(02): 151-158.
[13]	Sun Nuannuan, Li Yiming, Wang Dongxiang, Bao Mutai, Tong Linjuan. Mesoscopic Simulation Studies on the Self-assembly of Pluronic at Oil/Water Interface [J]. Acta Chimica Sinica, 2013, 71(02): 186-192.
[14]	Lu Weitao, Yang Jiping. Synthesis and Characterization of Tetraaniline-Polyethylene Glycol Block and Star-shaped Copolymers [J]. Acta Chimica Sinica, 2013, 71(01): 121-125.
[15]	Liu Hongyan, Guo Hongyu, Zhou Jian. Computer Simulations on the Anticancer Drug Delivery System of Docetaxel and PLGA-PEG Copolymer [J]. Acta Chimica Sinica, 2012, 70(23): 2445-2450.

含聚联烯的三嵌段共聚物的合成

Synthesis of Polyallene-Based ABA Triblock Copolymer

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments