Studies on the Complexation of di-Amide Based Macrocycles with Pyridine N-oxides

doi:10.6023/A1201061

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (12): 1385-1393.DOI: 10.6023/A1201061 Previous Articles Next Articles

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二酰胺大环化合物与吡啶N-氧化物的络合作用研究

杨登科^a, 曾志坚^b, 陈木娟^a, 潘绍武^a, 杨宇^a, 李媚^a, 雷春燕^a, 蒋腊生^a

a 华南师范大学化学与环境学院广州 510006;
b 华南师范大学实验中心广州 510006

投稿日期:2012-01-06 修回日期:2012-03-20 发布日期:2012-03-29
通讯作者: 蒋腊生 E-mail:jiang6128@yahoo.com.cn
基金资助:
国家自然科学基金(No. 21072066)资助项目.

Studies on the Complexation of di-Amide Based Macrocycles with Pyridine N-oxides

Yang Dengke^a, Zeng Zhijian^b, Chen Mujuan^a, Pan Shaowu^a, Yang Yu^a, Li Mei^a, Lei Chunyan^a, Jiang Lasheng^a

a School of Chemistry and Environment, South China Normal University, Guangzhou 510006;
b Research Resources Centre, South China Normal University, Guangzhou 510006

Received:2012-01-06 Revised:2012-03-20 Published:2012-03-29
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21072066).

A new cationic host molecule was synthesized by reaction of the di-amide based macrocycle with methyl iodide and the structure was confirmed by NMR, ESI-MS spectra. The complexation behavior of the di-amide based macrocycles with pyridine N-oxide guests was investigated by means of ESI-MS and ¹H NMR. The results showed that the cationic host can not only bind the pyridine N-oxide hosts to form 1∶ 1 pseudorotaxane-like complexes but also have much stronger binding ability than the corresponding neutral hosts.

Key words: macrocycles, host-guest chemistry, complexation, pseudorotaxane

Cite this article

Yang Dengke, Zeng Zhijian, Chen Mujuan, Pan Shaowu, Yang Yu, Li Mei, Lei Chunyan, Jiang Lasheng. Studies on the Complexation of di-Amide Based Macrocycles with Pyridine N-oxides[J]. Acta Chimica Sinica, 2012, 70(12): 1385-1393.

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二酰胺大环化合物与吡啶N-氧化物的络合作用研究

Studies on the Complexation of di-Amide Based Macrocycles with Pyridine N-oxides

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