Acta Chim. Sinica ›› 2015, Vol. 73 ›› Issue (3): 237-251.DOI: 10.6023/A14100702 Previous Articles     Next Articles

Special Issue: 新型太阳能电池

Review

全固态介观太阳能电池:从染料敏化到钙钛矿

荣耀光, 梅安意, 刘林峰, 李雄, 韩宏伟   

  1. 格兰泽尔介观太阳能电池研究中心 武汉光电国家实验室筹 华中科技大学 湖北 武汉 430074
  • 收稿日期:2014-10-13 出版日期:2015-03-14 发布日期:2015-01-29
  • 通讯作者: 韩宏伟 E-mail:hongwei.han@mail.hust.edu.cn

All-solid-state Mesoscopic Solar Cells: From Dye-sensitized to Perovskite

Rong Yaoguang, Mei Anyi, Liu Linfeng, Li Xiong, Han Hongwei   

  1. Michael Grätzel Center for Mesoscopic Solar Cells, Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Hubei, Wuhan 430074
  • Received:2014-10-13 Online:2015-03-14 Published:2015-01-29

As one of candidates of the next generation solar cells, mesoscopic solar cells offer a wide application prospect due to the advantages of abundant raw materials, simple fabrication process, high power conversion efficiency and so on. This review presents a brief overview on the progress of solid-state mesoscopic solar cells in new materials, new technologies and new concepts from dye-sensitized solar cells to perovskite solar cells. In 1998, Grätzel group firstly incorporated solid-state organic hole transport materials spiro-OMeTAD into dye-sensitized solar cell, and fabricated an all-solid-state dye-sensitized solar cell. Though this device only obtained an efficiency of 0.74%, all-solid-state dye-sensitized solar cells became an important direction in the field of mesoscopic solar cells. In 2012, Park group and Grätzel group employed a perovskite absorber (CH3NH3)PbI3 as the sensitizer, and spiro-OMeTAD as the hole collecting layer, developing an all-solid-state mesoscopic solar cell, which was also named perovskite solar cell, with the efficiency of up to 9.7%. Since then, mesoscopic perovskite solar cells based on perovskite materials quickly become a hot topic in the field of solar cell. Presently, the highest certificated power conversion efficiency of perovskite solar cells has reached to 20.1%. As a milestone in the development history of mesoscopic solar cells, perovskite solar cells still have many challenges in material developing, interface engineering, and device stability, and are expecting new breakthroughs in the future.

Key words: mesoscopic solar cells, all-solid-state, dye-sensitized, perovskite, counter electrode