Acta Chimica Sinica ›› 2020, Vol. 78 ›› Issue (9): 827-832.DOI: 10.6023/A20060227 Previous Articles     Next Articles



孙琦a, 肖丰收b   

  1. a 浙江大学化学工程与生物工程学院 杭州 310027;
    b 浙江大学化学系 浙江省应用化学重点实验室 杭州 310028
  • 投稿日期:2020-06-12 发布日期:2020-07-17
  • 通讯作者: 肖丰收
  • 作者简介:孙琦,博士,浙江大学"百人计划"研究员.2014年毕业于浙江大学化学系,导师肖丰收教授;2015~2019在美国南佛罗里达大学从事博士后研究,合作导师为马胜前教授;2019年9月入职浙江大学化学工程与生物工程学院联合化学反应工程研究所.主要从事有机多孔聚合物材料的设计合成及其在催化、吸附和分离领域的应用研究;肖丰收,浙江大学求是特聘教授,国家杰出青年基金获得者.1983和1986年在吉林大学化学系分别获得学士和硕士学位.1986~1990年,作为中日联合培养博士生,分别在吉林大学、大连化学物理研究所和日本北海道大学学习,并于1990获吉林大学博士学位;1993~1994年在美国加州大学戴维斯分校进行博士后研究.1993年任吉林大学化学系副教授,1996~2009年为吉林大学无机合成与制备化学国家重点实验室教授,2009年11月至今为浙江大学求是特聘教授.主要工作为沸石分子筛以及多孔材料的合成与催化性能研究.
  • 基金资助:

Exploration of Porous Organic Polymers as a Platform for Biomimetic Catalysis

Sun Qia, Xiao Feng-Shoub   

  1. a College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
    b Key Lab of Applied Chemistry of Zhejiang Province and Department of Chemistry, Zhejiang University, Hangzhou 310028, China
  • Received:2020-06-12 Published:2020-07-17
  • Supported by:
    Project supported by the Fundamental Research Funds for the Central Universities (No. 17221012001) and the National Natural Science Foundation of China (No. 21720102001).

Nature has served as a dominant source of inspiration in the area of chemistry, serving as prototypes for the design of materials with proficient performance. In this account, we present our effort to explore porous organic polymers (POPs) as a platform for the construction of biomimetic catalysts to enable new technologies to achieve efficient conversions. For each aspect, we firstly describe the chemical basis of nature, followed by presenting the principles and design strategies involved for functionalizing POPs along with a summary of critical requirements for materials, culminating in a demonstration of unique features of POPs. Our endeavors of using POPs to address the fundamental scientific problems related to biomimetic catalysis are then presented to show their enormous potential and capabilities for a wide range of catalytic transformations. To conclude, a personal perspective on the challenges and opportunities in this emerging field are presented.

Key words: porous organic polymers, biomimetic design, secondary interaction, flexible framework, wettability control