Acta Chimica Sinica ›› 1965, Vol. 31 ›› Issue (1): 38-41. Previous Articles     Next Articles

第五、六族元素的有机化合物在合成中应用的研究——Ⅰ.甲氧羰基亚甲基三苯基胂与羰基化合物的反应

黄耀曾1, 丁维钰2, 郑焕盛2   

  1. 1. 中国科学院有机化学研究所;
    2. 上海科学技术大学
  • 收稿日期:1963-12-14 出版日期:1965-01-15 发布日期:2013-06-03

STUDIES ON THE APPLICATION OF ELEMENTO-ORGANIC COMPOUNDS OF THE FIFTH AND SIXTH GROUPS IN ORGANIC SYNTHESES Ⅰ. REACTION OF CARBOMETHOXY-METHYLENE-TRIPHENYLARSINE WITH CARBONYL COMPOUNDS

HUANG YAO-TSENG1, TING WEI-YU2, CHENG HUAN-SHENG 2   

  1. 1. Institute of Organic Chemistry, Academia Sinica;
    2. University of Science and Technology of Shanghai
  • Received:1963-12-14 Online:1965-01-15 Published:2013-06-03

The reaction of triphenylarsine with methyl bromoacetate gave carbomethoxymethyl-triphenyl-arsonium bromide in 94% yield which on treating with sodium methoxide gave carbomethoxy-methylene-triphenylarsine.The latter reacted with several aromatic aldehydes, aromatic and alicyclic ketoses giving methyl ester of the corresponding α, β-unsaturated acid in good yield.