Studies on olefin-coordinating transition metal carbene complexes V: Synthesis and structure of new type of isomerized products of cyclohexadiene (dicarbonyl)(ethoxy(aryl)carbene)iron complexes

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (4): 418-420. Previous Articles Next Articles

Original Articles

含烯烃配体的过渡金属卡宾配合物的研究V:新型异构化的环己二烯(二羰基)[乙氧基(芳基)卡宾]铁配合物的合成和结构

陈家碧;雷桂馨;张泽莹;唐有祺

中国科学院上海有机化学研究所;北京大学物理化学研究所

发布日期:1987-04-15

Studies on olefin-coordinating transition metal carbene complexes V: Synthesis and structure of new type of isomerized products of cyclohexadiene (dicarbonyl)(ethoxy(aryl)carbene)iron complexes

CHEN JIABI;LEI GUIXIN;ZHANG ZEYING;TANG YOUQI

Published:1987-04-15

Abstract

Title compounds I (R = H, 3-Me, 4-Me, 4-MeO, 4-CF3) were prepared by treating 1,3-cyclohexadiene(tricarbonyl)iron with RC6H4L in Et2O at -50 to -60?followed by alkylation of the acylcarbonyl lithium salts with Et3OBF4 in aqueous solution at 0? The crystal structure of I (R = H) was determine

Key words: CRYSTAL STRUCTURE DETERMINATION, IRON COMPLEX, CARBONYL COMPLEX, CARBENE, STRUCTURAL ANALYSIS, TRANSITION METAL COMPLEX, CYCLOHEXADIENE P

CLC Number:

O627

Cite this article

CHEN JIABI;LEI GUIXIN;ZHANG ZEYING;TANG YOUQI. Studies on olefin-coordinating transition metal carbene complexes V: Synthesis and structure of new type of isomerized products of cyclohexadiene (dicarbonyl)(ethoxy(aryl)carbene)iron complexes[J]. Acta Chimica Sinica, 1987, 45(4): 418-420.

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含烯烃配体的过渡金属卡宾配合物的研究V:新型异构化的环己二烯(二羰基)[乙氧基(芳基)卡宾]铁配合物的合成和结构

Studies on olefin-coordinating transition metal carbene complexes V: Synthesis and structure of new type of isomerized products of cyclohexadiene (dicarbonyl)(ethoxy(aryl)carbene)iron complexes

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