Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (5): 445-449. Previous Articles     Next Articles

Original Articles

全氟及α,α-二氯多氟烷基亚磺酸盐的反应

黄维垣;陈俭龙   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1987-05-15

The reactions of perfluoro-and\a\,\a\-dichloropolyfluoro-alkanesulfinates

HUANG WEIYUAN;CHEN JIANLONG   

  • Published:1987-05-15

Reactions of the title compound with Br, KI, and iodine was described. E.g., heating Cl(CF2)4SO2Na and Cl(CF2)4CCl2SO2Na with Br and H2O at 80?C gave 82% Cl(CF2)4Br and 78% Cl(CF2)4CCl2Br resp.

Key words: SODIUM COMPOUNDS, BROMINATION REACTION, CHLOROHYDROCARBON, SULFONIC ACID, BROMOHYDROCARBON, FLUOROHYDROCARBON, IODINATION REACTION, IODOHYDROCARBON, SULFINIC ACID, PERFLUORO-HYDROCARBON

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