Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (2): 113-120. Previous Articles     Next Articles

Original Articles

聚苯乙烯在热力学半良溶剂丁酮中的稀溶液性质

黄天宝;MEYERHOFF,G.   

  1. 美因兹大学物理化学研究所
  • 发布日期:1988-02-15

The dilute solution properties of polystyrene in butanone as thermodynamically semigood solvent

HUANG TIANBAO;MEYERHOFF,G.   

  • Published:1988-02-15

The dilute solution of polystyrene (I) with narrow mol. wt. distribution and mol. wt. 1 ?104 to 18.9 ?106 in butanone at 20?was studied by light scattering, velocity sedimentation, and viscometry. The results were compared with the literature data of I in theta and good solvents. The unperturbed dimension, the interaction parameter, and the binary cluster integral values estimated based on Burchard-Stockmayer-Fixman-Yamakawa equation (1970) and on Baumann equation (1965) agreed well with the literature data.

Key words: SOLVENTS, POLYSTYRENE, POLYMER SOLUTION, BUTANONE, LIGHT SCATTERING TEST, VISCOMETRY, THERMODYNAMIC STATES, SETTLING

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