Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (2): 180-184. Previous Articles     Next Articles

Original Articles

有机硅化合物在α-D-葡二糖合成上的应用

费昌沛   

  1. 麦吉尔大学化学系
  • 发布日期:1990-02-15

Application of organosilicon compounds in the synthesis of -D-glucobiose

FEI CHANGPEI   

  • Published:1990-02-15

Triphenylsilyl group can be used as protective group for 1-OH in glucopyranose. The silyl group can be formed and deprotected readily in the presence of the p-nitrobenzoate group. The configuration at 1-C was not changed during the reactions. The use of triphenylsilyl group in the synthesis of a disaccharide I was demonstrated.

Key words: GLUCOSE, NITROBENZENE P, BENZENECARBOXYLIC ACID P, SILICON COMPOUNDS, ORGANO SILICON COMPOUNDS, TRIPHENYLMETHANE, PROTECTIVE GROUP, DISACCHARIDE

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