Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (6): 564-567. Previous Articles     Next Articles

Original Articles

亚硫酰氯还原的电催化研究

钟发平;杨汉西;查全性;盛蓉生   

  1. 中国科学院化学研究所;武汉大学化学系
  • 出版日期:1993-06-15 发布日期:1993-06-15

The electrocatalytic study of reduction of thionyl chloride

ZHONG FAPING;YANG HANXI;CHA QUANXING;SHENG RONGSHENG   

  • Online:1993-06-15 Published:1993-06-15

Micro-Raman mol. probe in combination with C powder microelectrodes was successfully used in the electrocatalysis study of SOCl2 reduction The discharge characteristics of Li/SOCl2 cells are usually limited by the large activation/polarization of SOCl2 on C surface. New catalysts octathiahydrophthalocyanine derivatives exhibited superior catalytic activity for reduction of SOCl2 on C surface. The catalytic mechanism and reaction on C cathodes were discussed.

Key words: PHTHALOCYANINE P, SEDIMENTS, MOLECULAR PROBE, CARBON ELECTRODES, ELECTRO-CATALYSIS, SULFUROUS ACID P, CATALYTIC ACTIVITY, ACYL CHLORIDES P, RAMAN SPECTROMETRY, SURFACE MORPHOLOGY

CLC Number: