Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (15): 1461-1464. Previous Articles     Next Articles

Reports

溶胶-凝胶法制备桥式聚倍半硅氧烷/SiO2光学防潮膜

杨东江1 2,徐耀1,张磊1 2,翟尚儒1 2,吴东1,孙予罕*1   

  1. (1中国科学院山西煤炭化学研究所 煤转化国家重点实验室 太原 030001 )
    (2中国科学院研究生院 北京 100039 )
  • 收稿日期:2004-10-09 修回日期:2005-04-11 出版日期:2005-08-15 发布日期:2010-12-10
  • 通讯作者: 孙予罕

Preparation of Bridged Polysilsesquioxane/SiO2 Optical Moisture-Proof Film via Sol-Gel Method

YANG Dong-Jiang1,2, XU Yao1, ZHANG Lei1,2,ZHAI Shang-Ru1,2, WU Dong1, SUN Yu-Han*1   

  1. (1 State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001)
    (2 Graduate School of Chinese Academy of Sciences, Beijing 100039)
  • Received:2004-10-09 Revised:2005-04-11 Online:2005-08-15 Published:2010-12-10
  • Contact: SUN Yu-Han

A new bridged precursor of m-xylylene diureidopropyltriethoxysilane (m-XDUPTEOS) was firstly synthesized. Utilizing the mixture of the present new precursor and tetraethoxysilane (TEOS) as silica source, a series of polysilsesquioxane/SiO2 hybrid sols have been obtained via adjusting molar ratio of both reagents, and then corresponding hybrid films have also been prepared by spinning-coating technique. The optical property, surface morphology and the thermal stability of these hybrid films were thoroughly studied by UV-Vis, AFM and TGA methods, respectively, indicating that these hybrid films all had smooth surface, fine thermal stability, excellent optical transmittance and moisture-proof ability.

Key words: sol-gel, bridged polysilsesquioxane, optical moisture-proof film