Synthesis and Photo-Initiative Properties of [1,5-Di-(N,N’-dialkylamino)- anthraquinone Derivatives Containing  Functional Acryloyl Groups]

Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (22): 2518-2524. Previous Articles Next Articles

Original Articles

具有分子内电子转移特征的氨基蒽醌类有机化合物的合成及光物理性质研究

韩建国a,b 申凯华*,a 赵德丰a 王光宇a 邵玉昌b

(a大连理工大学精细化工国家重点实验室大连 116012)
(b大连化工研究设计院大连 116023)

投稿日期:2008-04-09 修回日期:2008-05-22 发布日期:2008-11-28
通讯作者: 申凯华

Synthesis and Photo-Initiative Properties of [1,5-Di-(N,N’-dialkylamino)- anthraquinone Derivatives Containing Functional Acryloyl Groups]

HAN, Jian-Guo ^a,b SHEN, Kai-Hua ^*,a ZHAO, De-Feng ^aWANG, Guang-Yu ^a SHAO, Yu-Chang ^b

(a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012)
(b Dalian Institute of Research and Design of Chemical Industry, Dalian 116023)

Received:2008-04-09 Revised:2008-05-22 Published:2008-11-28
Contact: SHEN, Kai-Hua

Abstract

Some l,5-di-(N,N’-dialkylamino)-anthraquinones and their derivatives containing functional acryloyl groups were synthesized and characterized by 1H NMR, IR and MS. The photo-initiating systems composed of 1,5-di-N,N’-dialkylamino-anthraquinone derivatives or 1,5-di-(N,N’-dialkylamino)-anthraquinone containing acryloyl groups with HABI exhibited faster photobeaching rate and higher initiating efficiency under 500 nm visible light, thus can be used as photo-absorbing and photoinitiating materials which are suitable for Ar＋.

Key words: charge transfer system, aminoanthraquinone, photo-bleach, photopolymerization, FTIR

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具有分子内电子转移特征的氨基蒽醌类有机化合物的合成及光物理性质研究

Synthesis and Photo-Initiative Properties of [1,5-Di-(N,N’-dialkylamino)- anthraquinone Derivatives Containing Functional Acryloyl Groups]

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具有分子内电子转移特征的氨基蒽醌类有机化合物的合成 及光物理性质研究

Synthesis and Photo-Initiative Properties of [1,5-Di-(N,N’-dialkylamino)- anthraquinone Derivatives Containing Functional Acryloyl Groups]

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

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Metrics

Comments

具有分子内电子转移特征的氨基蒽醌类有机化合物的合成及光物理性质研究