Acta Chimica Sinica ›› 2008, Vol. 66 ›› Issue (5): 563-566. Previous Articles     Next Articles

Original Articles

四叔丁基萘酞菁铅化合物的非线性和光限幅特性

刘大军*,何兴权,高正国,段潜,周奋国   

  1. (长春理工大学化学与环境工程学院 长春 130022)
  • 收稿日期:2007-08-03 修回日期:2007-10-07 出版日期:2008-03-14 发布日期:2008-03-14
  • 通讯作者: 刘大军

Nonlinear and Optical Limiting Properties of Tetra tert-Butylnaphthalocyanine Lead

LIU Da-Jun* ,HE Xing-Quan, GAO Zheng-Guo ,DUAN Qian ,ZHOU Fen-Guo   

  1. (College of Chemical and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022)
  • Received:2007-08-03 Revised:2007-10-07 Online:2008-03-14 Published:2008-03-14
  • Contact: LIU Da-Jun

The compound of tetra tert-butylnaphthalocyanine lead was synthesized. The structure of the compound was characterized by means of elemental analysis, infrared spectrum and hydrogen nuclear magnetic resonance spectrum. A frequency-doubled Q switched Nd:YAG pulse laser system with ns/ps laser pulse was used for studying the nonlinear and optical limiting properties of the synthesized compound at the wavelength of 532 nm. The nonlinear refracting index, n2, and third-order nonlinear polarizability, χ(3) were determined to be 2.54×10-11 and 9.51×10-12 esu, respectively. The molecular polarizability of the compound γ' was calculated to be 3.3×10-29 esu. When visible light transmittance was 69%, the limiting threshold value was 1522 mJ/cm2, the clamp value was 553 mJ/cm2, and the ratio of absorption sectional area of effective excited state to that of ground state was 3.16.

Key words: nonlinear optics, Z-scan, naphthalocyanine