Synthesis, Crystal Structure and Studies on Properties of A Novel Type of D-π-D-π-D Ferrocene Derivative

doi:10.6023/A1104277Z

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (21): 2543-2549.DOI: 10.6023/A1104277Z Previous Articles Next Articles

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一种新型D-π-D-π-D型二茂铁衍生物的合成、晶体结构和性质研究

肖陆飞^1,2，陈晨¹，吴杰颖*^,1，田玉鹏¹，金葆康*^,1

(¹安徽大学化学化工学院合肥 230039)
(²滁州职业技术学院滁州 239000)

投稿日期:2011-04-27 修回日期:2011-06-08 发布日期:2011-07-05
通讯作者: 肖陆飞 E-mail:xlf3345@163.com
基金资助:
国家自然科学基金;教育部新世纪优秀人才基金;安徽省高校省级自然科学基金项目

Synthesis, Crystal Structure and Studies on Properties of A Novel Type of D-π-D-π-D Ferrocene Derivative

Xiao Lufei^1,2 Chen Chen¹ Wu Jieying*^,1 Tian Yupeng¹ Jin Baokang*^,1

(¹College of Chemistry and Chemical Engineering, Anhui University, Hefei 230039)
(²Chuzhou Vocational And Technical College, Chuzhou 239000)

Received:2011-04-27 Revised:2011-06-08 Published:2011-07-05

A novel solid D-π-D-π-D ferrocene derivative: 1,4-dibutoxy-2,5-bis(2-ferrocenylvinyl)benzene, was synthesized through Wittig reaction, and it has been characterized by ¹H NMR, IR and MS. The crystal structure of the compound has been characterized by single crystal X-ray diffraction analysis. It crystallizes in monoclinic crystal system and C2/c space group. Redox process of the compound was studied using cyclic voltammetry, rapid-scan time-resolved FT-IR spectroscopy methods and cyclic voltabsorptometry (CVAs), and the two-photon absorption of the compound was measured by the Z-scan technique at 532 nm. The results show that there is a good electronic delocalization in the molecule and two-photon absorption response for it.

Key words: ferrocene derivative, Wittig reaction, crystal structure, redox process, nonlinear optics

Cite this article

XIAO Lu-Fei, CHEN Chen, WU Jie-Ying, TIAN Yu-Peng, JIN Bao-Kang. Synthesis, Crystal Structure and Studies on Properties of A Novel Type of D-π-D-π-D Ferrocene Derivative[J]. Acta Chimica Sinica, 2011, 69(21): 2543-2549.

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一种新型D-π-D-π-D型二茂铁衍生物的合成、晶体结构和性质研究

Synthesis, Crystal Structure and Studies on Properties of A Novel Type of D-π-D-π-D Ferrocene Derivative

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