Preparation of Co3O4 Catalysts by a Solid-state Reaction for Total Oxidation of Toluene

doi:10.6023/A1104062

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (01): 39-44.DOI: 10.6023/A1104062 Previous Articles Next Articles

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固相法制备纳米Co₃O₄催化剂及其催化甲苯完全氧化性能

熊德胜, 秦枫, 徐华龙, 沈伟

上海市分子催化和功能材料重点实验室, 复旦大学先进材料实验室, 复旦大学化学系, 上海 200433

投稿日期:2011-04-06 修回日期:2011-07-27 发布日期:2012-02-25
通讯作者: 沈伟 E-mail:wshen@fudan.edu.cn
基金资助:
863重点计划(No.2009AA033701)、上海市科学技术委员会基金(Nos.08DZ2270500,09DZ2271500)资助项目.

Preparation of Co₃O₄ Catalysts by a Solid-state Reaction for Total Oxidation of Toluene

Xiong Desheng, Qin Feng, Xu Hualong, Shen Wei

Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Laboratory of Advanced Materials, Department of Chemistry, Fudan University, Shanghai 200433

Received:2011-04-06 Revised:2011-07-27 Published:2012-02-25
Supported by:
Project supported by the Chinese Ministry of Science and Technology,the“863”State Key Research Project(No.2009AA033701)and Science and Technology Commission of Shanghai Municipality(Nos.08DZ2270500,09DZ2271500).

Highly active Co₃O₄ catalysts(Co₃O₄-SR)are synthesized by a simple and environmentally friendly solid-state reaction.Compared with Co₃O₄ made by precipitation and citrate methods,Co₃O₄-SR catalysts possess lager surface area,smaller particle size,weaker surface Co—O bond and more surface de- fects.Co₃O₄-SR catalysts exhibit high activity and stability for total oxidation of toluene,with a toluene conversion of 95%at 230℃without any observable trend of deactivation in 60h.

Key words: toluene, total oxidation, cobalt oxide, solid-state reaction

Cite this article

Xiong Desheng, Qin Feng, Xu Hualong, Shen Wei. Preparation of Co₃O₄ Catalysts by a Solid-state Reaction for Total Oxidation of Toluene[J]. Acta Chimica Sinica, 2012, 70(01): 39-44.

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固相法制备纳米Co₃O₄催化剂及其催化甲苯完全氧化性能

Preparation of Co₃O₄ Catalysts by a Solid-state Reaction for Total Oxidation of Toluene

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固相法制备纳米Co3O4催化剂及其催化甲苯完全氧化性能