Acta Chimica Sinica ›› 1997, Vol. 55 ›› Issue (6): 521-526.     Next Articles

Original Articles

中性配体存在下(OEP)Co的电化学和光谱电化学研究

林祥钦;严川伟   

  1. 中国科学院长春应用化学研究所电分析化学实验室国家电化学和;光谱研究分析 中心
  • 发布日期:1997-06-15

Electrochemical and spectroelectrochemical study of (OEP)Co in the presence of acrylonitrile, ethanol, N, N-dimethylformamide and dimethylsulfoxide in dichloroethane solution

Lin Xiangqin;Yan Chuanwei   

  • Published:1997-06-15

The ligand effects of acrylonitrile, EtOH, DMF and DMSO on the electrochemical oxidation reactions of (OEP)Co were investigated by CV monitored electrochemical titration and in-situ thin-layer spectroelectrochemical method. The formation constants of (OEP)Co(Ⅲ) with these molecules were calculated. The magnitude of the values shows the order of acrylonitrile

Key words: METALLOPORPHYRIN, ELECTROCHEMISTRY, TITRATION, CYCLOVOLTAMGRAPH

CLC Number: