The synthesis of 10-tellurabenzo-15-crown-5 platinum complex and its catalytic hydrosilylation behavior

Acta Chimica Sinica ›› 1993, Vol. 51 ›› Issue (12): 1170-1173. Previous Articles Next Articles

Original Articles

10-碲杂苯并-15-冠-5铂配合物的合成及其催化硅氢化性能

徐汉生;李卫平;卢雪然;刘秀芳

武汉大学化学系

发布日期:1993-12-15

The synthesis of 10-tellurabenzo-15-crown-5 platinum complex and its catalytic hydrosilylation behavior

XU HANSHENG;LI WEIPING;LU XUERAN;LIU XIUFANG

Published:1993-12-15

Abstract

The synthesis of the 1st telluracrown ether Pt complex: 10-tellurabenzo-15-crown-5-Pt, is described. The influences of the nature of olefins, reaction temperature, the amount of title complex used, reaction atomsphere and introducing Hg on its catalytic activity for the hydrosilylation of olefins by triethoxysilane were studied. Its catalytic hydrosilylation activity is lower than that of the corresponding selenacrown ether Pt complex, but toward certain olefins, such as Ph allyl ether, it still exhibits high catalytic activity.

Key words: CROWN ETHER COMPOUNDS, ALKENE, PLATINUM COMPLEX, SILANE, HYDROSILYLATION

CLC Number:

O627
O647

Cite this article

XU HANSHENG;LI WEIPING;LU XUERAN;LIU XIUFANG. The synthesis of 10-tellurabenzo-15-crown-5 platinum complex and its catalytic hydrosilylation behavior[J]. Acta Chimica Sinica, 1993, 51(12): 1170-1173.

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10-碲杂苯并-15-冠-5铂配合物的合成及其催化硅氢化性能

The synthesis of 10-tellurabenzo-15-crown-5 platinum complex and its catalytic hydrosilylation behavior

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