Simultaneous polymerization and formation of polyphenylacetylene films

Abstract

Transition metal (V, Cr, Mn, Fe, Co, Ni) naphthenate-(iso-Bu)3Al catalyst systems could promote simultaneous polymerisation and formation of poly(phenylacetylene) (I) films at room temperature in hydrogenated gasoline-PhMe mixed solvent. The activity of the catalysts decreased in the following order: Fe > Cr > Co > Mn > V > Ni. The effect of solvent, catalyst, and polymerisation conditions on the formation of I was studied. The activation energy for polymerisation using Fe naphthenate-(iso-Bu)3Al catalyst was 20 kJ/mol. I films could be yellow, orange, red, and/or brown color and had rich cis-content, high mol. wt., high structural stability, and high crystallinity as well as semiconductor characteristics (109 W.cm).

Key words: COBALT COMPOUNDS, ISOBUTYL GROUP, ALUMINIUM COMPOUNDS, NICKEL COMPOUNDS, IRON COMPOUNDS, MANGANESE COMPOUNDS, CADMIUM COMPOUNDS, VANADIUM COMPOUNDS, NAPHTHENATE, POLYMER FILMS

CLC Number:

O631.3

Cite this article

YANG MUJIE;ZHANG FUYAO;ZHAO JIAN;SHEN ZHIQUAN. Simultaneous polymerization and formation of polyphenylacetylene films[J]. Acta Chimica Sinica, 1990, 48(10): 1036-1042.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Dou Jianmin;Hu Chunhua;Yao Hiajun$DLi, Yuesheng$ESun Jie;Zheng Peiju. Synthesis and Crystal Structure of Two Closo Twleve-vertex Dinickeladodecaborane Clusters [J]. Acta Chimica Sinica, 2003, 61(7): 1006-1013.
[2]	Xu Hai;Que Guohe;Wang Jiqian;Yu Daoyong;Zhang Jing;Xie Yaning;Hu Tiandou. Structural Characterization by XAFS Spectroscopy of Non-Porphyrin Nickel in Liaohe Vacuum Residue [J]. Acta Chimica Sinica, 2003, 61(3): 450-453.
[3]	Peng Zhaokuai;Zhang Xiaohong;Wu Shikang. Study on the Photo-induced Electron Transfer and the Exciplex Formation of Some Novel Blue Emission Dyes with Aluminum Tris (8- hydroxyquinoline) Using Fluorescent Spectra Methods [J]. Acta Chimica Sinica, 2003, 61(11): 1734-1739.
[4]	Ren Jie;Chen Zhida. Application of Density Functional Theory in Molecular Magnetism [J]. Acta Chimica Sinica, 2003, 61(10): 1537-1542.
[5]	Wang Lijun;Guo Changwen;Tian Ting;Wu Haoqing. Catalytic Synthesis of Bamboo-shaped Nitrogen-doped Carbon Nanotubes [J]. Acta Chimica Sinica, 2003, 61(10): 1664-1666.
[6]	Liu Yingchun;Wang Qi. Synthesis, Characterization and Structure of P(OC_2H_5)_3 Substituted Derivatives of Co_6-Carbonyl Cluster [J]. Acta Chimica Sinica, 2002, 60(9): 1644-1648.
[7]	Xu Wen;Fang Qi;Xue Gang;Yu Wentao;Liu Guoqun;Zhang Deqing;Xu Wei;Xu Cuiying;Zhang Jinbiao. Synthesis, Structure and Conductivity of Molecular Conductor (PyH) [Ni(dmit)_2]_2 [J]. Acta Chimica Sinica, 2002, 60(12): 2153-2158.
[8]	Dou Jianmin;Hu Chunhua;Yao Haijun;Li Yuesheng;Jin Ruoshui;Zheng Peiju. Synthesis and Crystal Structure of closo Twelve-vertex Cluster [(μ- Cl)(Ph_2PC_6H_4)_2Ni_2B_(10)H_6Cl(PPh_3)] [J]. Acta Chimica Sinica, 2002, 60(11): 1993-1998.
[9]	Wang Hua;Wu Chaoyang;Wang Qichang;Shen Guoli;Yu Ruqin. Studies on a novel piezoelectric immunosensor based on plasma polymerized film for the schistosoma-japonicum [J]. Acta Chimica Sinica, 2001, 59(9): 1457-1463.
[10]	Meng Xiangru;Li Linke;Song Yinglin;Zhu Yu;Du Chenxia;Fan Yaoting;Hou Hongwei. Synthesis, crystal structure and nonlinear optical properties of a manganese supramolecular compound [J]. Acta Chimica Sinica, 2001, 59(8): 1277-1282.
[11]	Li He;Liang Qi;Tang Shuihua;Gao Lizhen;Chen Zhaoyong;Zhang Bolan;Yu Zuolong. A study on production of carbon nanotubes by decomposition of CH4 over the pre-reduced catalysts LaNiO3, La4Ni3O10, La3Ni2O7 and La2NiO4 [J]. Acta Chimica Sinica, 2001, 59(8): 1236-1240.
[12]	Li Junqian;Xiang Shengchang;Zhang Yongfan. Studieson the band structures, the relationship of magnetism and distortion of CaNiN by density functional calculations [J]. Acta Chimica Sinica, 2001, 59(6): 883-889.
[13]	Guo Hongsheng;He Xiwen;Gan Yuan;Li Wenyou;Liang Hong. Study of selective binding characteristics and transport properties of trimethoprim molecular template polymer membrane [J]. Acta Chimica Sinica, 2001, 59(2): 262-267.
[14]	Du Hongbing;Liao Libing;Yang Zanzhong;Ma Zhesheng;Xiong Ming. Hydrothermal synthesis and structure characterization of a novel open-framework vanadium phosphate (H3NCH2CH2NH3)3 [ (VO)4(PO4)2(HPO4) 4 [J]. Acta Chimica Sinica, 2001, 59(2): 274-278.
[15]	Sun Dejun;Hou Wanguo;Liu Shangying;Zhang Baoqing;Zhang Chunguang. Thixotropic properties of aqueous dispersions of positively charged Al/Mg mixed metal hydroxide particles [J]. Acta Chimica Sinica, 2001, 59(2): 163-167.

苯乙炔直接成膜聚合