Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (11): 1109-1112. Previous Articles     Next Articles

Original Articles

多氟芳烃的亲核反应II: 一氯五氟苯的亲核环化

葛文正;胡里清;黄维垣   

  1. 中国科学院上海有机化学研究所
  • 发布日期:1988-11-15

The nucleophilic reaction of polyfluoroaromatic compounds II: The nucleophilic cyclization of chloropentafluorobenzene

GE WENZHENG;HU LIQING;HUANG WEIYUAN   

  • Published:1988-11-15

The results of cyclization reaction between chloropentafluorobenzene and bifunctional nucleophiles, such as RCH2CH2OH (R = OH, NHMe, NHEt), HN(CH2CH2OH)2, and NH2CH2CH2NH2, were reported. Thus, stirring C6F5Cl with MeNHCH2CH2OH and NaH in DMF at 60?for 3 h gave cyclization products I and II.

Key words: BENZENE P, CYCLIZATION, FLUOROHYDROCARBON, NUCLEOPHILIC REACTION, CHLOROBENZENE P

CLC Number: