Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (2): 163-166. Previous Articles     Next Articles

Original Articles

[Cr(H2O)3(NCS)3](18-冠-6)的分子和晶体结构

张文兴;樊悦朋;孔庆池;徐宏伟   

  1. 山东大学化学系
  • 发布日期:1989-02-15

The molecular and crystal structure of [Cr(H2O)3(NCS)3](18-crown-6)

ZHANG WENXING;FAN YUEPENG;KONG QINGCHI;XU HONGWEI   

  • Published:1989-02-15

The title compound is orthorhombic, space group Pcmn, with a 9.722(2), b 13.023(4), and c 19.713(6) ? dc = 1.45 for Z = 4. Final R = 0.064. Atomic coordinates are given. The Cr is octahedrally coordinated by 3 isothiocyanates and 3 H2O mols. The 18-crown-6 is H bonded.

Key words: CRYSTAL STRUCTURE, MOLECULAR STRUCTURE, CROWN ETHER COMPOUNDS, STRUCTURAL ANALYSIS, AQUO COMPLEX, TRANSITION METAL COMPLEX, CHROMIUM COMPLEX, ISOTHIOCYANIC ACID

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