Coordination chemistry of organometallic polydentate ligand :  Formation of binuclear complexes for the stabilization of Carbene-Iron (0) compound

Acta Chimica Sinica ›› 1997, Vol. 55 ›› Issue (3): 302-305. Previous Articles Next Articles

Original Articles

金属有机多齿配体配位化学: 双核化合物的形成促使铁卡宾键的稳定化

匡善明;孙丽娟;张正之

云南大学元素有机化学实验室

发布日期:1997-03-15

Coordination chemistry of organometallic polydentate ligand : Formation of binuclear complexes for the stabilization of Carbene-Iron (0) compound

KUANG SHANMING;SUN LIJUAN;ZHANG ZHENGZHI

Published:1997-03-15

Abstract

Mononuclear compounds MXn[MXn=HgCl2, HgI2, CdCl2, K2Zn(SCN)4] react with the 1,3-dithiol-2-ylidene complex Fe(Ph2Pyy)2(CO)2[CS2C2(CO2Me)2] to produce the stable binuclear carbene complexes FeM(μ-Ph2PPy)2[CS2C2(CO2Me)2](CO)2X2[Ph2PPy=2- diphenylphosphino pyridine]. These complexes were characterized by IR, ^3^1P NMR and elemental analysis.

Key words: STABILITY, PYRIDINE P, INFRARED SPECTROPHOTOMETRY, ELEMENTAL ANALYSIS, IRON COMPLEX, CARBENE, MERCURY CHLORIDE, CADMIUM CHLORIDE, PHOSPHORUS 31 MAGNETIC RESONANCE SPECTROMETRY, MERCURIC IODIDE

CLC Number:

O611.662

Cite this article

KUANG SHANMING;SUN LIJUAN;ZHANG ZHENGZHI. Coordination chemistry of organometallic polydentate ligand : Formation of binuclear complexes for the stabilization of Carbene-Iron (0) compound[J]. Acta Chimica Sinica, 1997, 55(3): 302-305.

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金属有机多齿配体配位化学: 双核化合物的形成促使铁卡宾键的稳定化

Coordination chemistry of organometallic polydentate ligand : Formation of binuclear complexes for the stabilization of Carbene-Iron (0) compound

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