Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (10): 997-1002. Previous Articles     Next Articles

Original Articles

水溶性β-环糊精交联聚合物与分析试剂客体包结反应的研究

苏小笛;刘六战;沈含熙   

  1. 南开大学化学系
  • 发布日期:1996-10-15

Studies on the inclusive reactions of water-soluble β-cyclodextrin cross-linking polymer with guest parts of analytical reagents

SU XIAODI;LIU LIUZHAN;SHEN HANXI   

  • Published:1996-10-15

A water-soluble cross-linking polymer of β-CD with epichlorohydrin was synthesized. The actions of polymer are different from β-CD when it reacts with the organic guests to form inclusion complexes. The multiunits of β-CD containing in the polymer possessed synergic effect on different guest parts of organic molecules. In this paper the inclusion reactions of polymer with a series of organic analytical reagents containing two guest groups have been studied in detail. The results showed that the polymer provided more specific effects and functions than β-CD on the enhancement of solubility, absorption and fluorescence spectra. It is possible to be a new molecular recognition method for certain organic compound containing two aromatic guest groups.

Key words: CYCLODEXTRIN, CROSSLINKED POLYMER, INCLUSION COMPLEXATIONS, ANALYTICAL REAGENT

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