A study on coupled chemiluminescence reaction of Ru(1,10-phenanthroline)~3^2^+-organic acid-Ce(Ⅳ)

Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (10): 1003-1008. Previous Articles Next Articles

Original Articles

钌(Ⅱ)-邻菲咯啉-有机酸-Ce(Ⅳ)偶合化学发光反应及其应用研究

何治柯;马容明;罗庆尧;余席茂;曾云鹗

武汉大学化学系

发布日期:1996-10-15

A study on coupled chemiluminescence reaction of Ru(1,10-phenanthroline)~3^2^+-organic acid-Ce(Ⅳ)

HE ZHIKE;MA RONGMING;LUO QINGYAO;YU XIMAO;ZENG YUNE

Published:1996-10-15

Abstract

Reactions of 16 organic acids with Ru(phen)~3^2^+ (phen=1,10-phenanthroline) and Ce(Ⅳ) were examined for chemiluminescence (CL) light emission. Organic acids with C=O or OH group were found capable of increasing the CL light emission. CL intensity were linearly related to the concentration of them. The method has been satisfactorily applied to determine free oxalic acid in diethyl oxalate and oxalate in human urine. A coupled Cl reaction mechanism is presented.

Key words: ORGANIC ACID, OXALIC ACID, HYDROXYCARBOXYLIC ACIDS, CHEMILUMINESCENCE ANALYSIS, RUTHENIUM, CHEMILUMINESCENCE REACTION, CARBONYL GROUP, PHENANTHROLINE

CLC Number:

O656

Cite this article

HE ZHIKE;MA RONGMING;LUO QINGYAO;YU XIMAO;ZENG YUNE. A study on coupled chemiluminescence reaction of Ru(1,10-phenanthroline)~3^2^+-organic acid-Ce(Ⅳ)[J]. Acta Chimica Sinica, 1996, 54(10): 1003-1008.

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钌(Ⅱ)-邻菲咯啉-有机酸-Ce(Ⅳ)偶合化学发光反应及其应用研究

A study on coupled chemiluminescence reaction of Ru(1,10-phenanthroline)~3^2^+-organic acid-Ce(Ⅳ)

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