Investigation on the Conformation Transition of Regenerated Silk Fibroin Films under Thermal Treatment by two-dimensional (2D) correlation FT-IR spectroscopy

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (21): 2127-2130. Next Articles

二维相关红外光谱研究再生蚕丝蛋白膜的构象与温度之间的关系

彭显能, 陈新, 武培怡, 邵正中

复旦大学高分子科学系, 教育部聚合物分子工程重点实验室, 上海, 200433

投稿日期:2004-04-12 修回日期:2004-06-05 发布日期:2014-02-17
通讯作者: zzshao@fudan.edu.cn
作者简介:邵正中,E-mail:zzshao@fudan.edu.cn
基金资助:
国家自然科学基金(Nos.50373006,20244005,20274010,20221402)、教育部优秀青年教师资助计划项目.

Investigation on the Conformation Transition of Regenerated Silk Fibroin Films under Thermal Treatment by two-dimensional (2D) correlation FT-IR spectroscopy

PENG Xian-Neng, CHEN Xin, WU Pei-Yi, SHAO Zheng-Zhong

Department of Macromolecular Science, The Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433

Received:2004-04-12 Revised:2004-06-05 Published:2014-02-17

Abstract

With the advantage of two dimensional (2D) correlation FT-IR spectroscopy, the conformation transition of regenerated silk fibroin film was studied under thermal treatment. The results showed that the conformation changed when the film was heated from 130 to 220℃ as well as maintained at 180℃ for different time courses. It was also found that the conformation response order was random coil prior to β-sheet and α-helix.

Key words: two-dimensional correlation FTIR spectroscopy, Bombyx mori, silk protein, film

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PENG Xian-Neng, CHEN Xin, WU Pei-Yi, SHAO Zheng-Zhong. Investigation on the Conformation Transition of Regenerated Silk Fibroin Films under Thermal Treatment by two-dimensional (2D) correlation FT-IR spectroscopy[J]. Acta Chimica Sinica, 2004, 62(21): 2127-2130.

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二维相关红外光谱研究再生蚕丝蛋白膜的构象与温度之间的关系

Investigation on the Conformation Transition of Regenerated Silk Fibroin Films under Thermal Treatment by two-dimensional (2D) correlation FT-IR spectroscopy

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