Polyaniline-graphene Hollow Spheres based on Graphene Stabilized Pickering Emulsions

doi:10.6023/A16110624

Acta Chim. Sinica ›› 2017, Vol. 75 ›› Issue (4): 391-397.DOI: 10.6023/A16110624 Previous Articles Next Articles

Article

Pickering乳液法制备聚苯胺-石墨烯空心微球

郑媛, 罗静, 魏玮, 刘晓亚

江南大学化学与材料工程学院食品胶体与生物技术教育部重点实验室无锡 214122

投稿日期:2016-11-25 发布日期:2017-03-07
通讯作者: 罗静,E-mail:jingluo19801007@126.com E-mail:jingluo19801007@126.com
基金资助:
项目受国家自然科学基金（No.51573072）和江苏省“六大人才高峰”（XNY-012）资助.

Polyaniline-graphene Hollow Spheres based on Graphene Stabilized Pickering Emulsions

Zheng Yuan, Luo Jing, Wei Wei, Liu Xiaoya

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122

Received:2016-11-25 Published:2017-03-07
Contact: 10.6023/A16110624 E-mail:jingluo19801007@126.com
Supported by:
Project supported by the National Natural Science Foundation of China (No. 51573072) and the Six Talents Peak Project of Jiangsu Province (XNY-012).

1. Polyaniline-graphene Hollow Spheres based on Graphene Stabilized Pickering Emulsions.PDF(639KB)

Abstract

In recent years, hybrid nanomaterials of graphene and polyaniline have attracted extensive interest and have been considered as promising electrode materials for supercapacitor combining the advantages of both materials with synergistic effects. In contrast to the well-developed two-dimensional planar structure of graphene-PANI, the pursuit of hollow gra-phene-PANI hybrid structure is relatively less investigated. The hollow micro/nanostructured graphene-PANI materials with the nanoscale shell, inner cavity and pore structures, is highly expected to exhibit remarkable enhanced supercapacitor performance owing to the enhanced specific surface area and shortened diffusion length for both charge and mass transport. In this work, a novel kind of graphene-polyaniline hollow capsules (PANI-SGR HS) was prepared via Pickering emulsion polymerization using sulfonated graphene (SGR) as Pickering stabilizer. Amphiphilic sulfonated graphene is prepared by a covalent modification and used to stabilize oil phase containing aniline monomer. Aniline molecules were adsorbed to the oil-water interface owing to the electrostatic interaction between amino groups of aniline and sulfonic groups of SGR, which subsequently underwent interfacial polymerization at the oil/water interface upon the addition of initiator ammonium persulfate (APS). The effects of the sulfonation degree of graphene, the SGR concentration as well as the oil/water volume ratio on the stability and morphology of SGR stabilized emulsions were investigated in detail. The SGR with appropriate sulfonation degree can produce stable emulsions. The average diameter of the emulsion droplet decreased with the increasing concentration of SGR stabilizer. The emulsion stability can be improved with the increased water phase infraction. After polymerization of aniline and removal of the oil phase, three-dimensional hollow graphene-polyaniline sphere (PANI-SGR HS) was obtained. The morphology of PANI-SGR HS was observed by scanning electron microscopy (SEM). The special hollow sphere structure not only enlarged the liquid contact area but also improved charge carrier mobility. The hollow sphere modified electrode exhibited excellent performance with a specific capacitance of 480.59 F·g^-1 at 1 A·g^-1, which is much higher than 251 F·g^-1 of the common two-dimensional stacked graphene-polyaniline film. This novel three-dimensional PANI-SGR HS material may have potential applications in energy storage.

Key words: graphene composite, polyaniline, Pickering stabilizer, hollow sphere, electrochemistry

Cite this article

Zheng Yuan, Luo Jing, Wei Wei, Liu Xiaoya. Polyaniline-graphene Hollow Spheres based on Graphene Stabilized Pickering Emulsions[J]. Acta Chim. Sinica, 2017, 75(4): 391-397.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Zhu, Y.; Murali, S.; Cai, W.; Li, X.; Suk, J.; Potts, J.; Rouff, R. Adv. Mater. 2010, 22, 3906.
[2] He, Q.; Wu, S.; Yin, Z.; Zhang, H. Chem. Sci. 2012, 3, 1764.
[3] Yang, L.; Tang, Y.; Yan, D.; Liu, T.; Liu, C.; Luo, S. ACS Appl. Mater. Interfaces 2015, 8, 169.
[4] Tong, Z.; Fang, S.; Zheng, H.; Zhang, X. Acta Chim. Sinica 2016, 74, 185. (童震坤, 方姗, 郑浩, 张校刚, 化学学报, 2016, 74, 185.)
[5] Gao, H.; Lu, Q.; Liu, N.; Wang, X.; Wang, F. J. Mater. Chem. A 2015, 3, 7215.
[6] Wang, L.; Lu, X.; Lei, S.; Song, Y. J. Mater. Chem. A 2014, 2, 4491.
[7] Luo, J.; Chen, Y.; Ma, Q.; Liu, R.; Liu, X. J. Mater. Chem. C 2014, 2, 4818.
[8] Domingues, S. H.; Salvatierra, R. V.; Oliveira, M. M.; Zarbin, A. J. Chem. Commun. 2011, 47, 2592.
[9] Sun, J.; Zhu, Z.; Lai, J.; Luo, J.; Liu, X. Chem. J. Chin. Univ. 2015, 36, 581. (孙军, 朱正意, 赖健平, 罗静, 刘晓亚, 高等学校化学学报, 2015, 36, 581.)
[10] Fan, X.; Yang, Z.; Liu, Z. Chin. J. Chem. 2016, 34, 107.
[11] Du, P.; Liu, H. C.; Yi, C.; Wang, K.; Gong, X. ACS Appl. Mater. Interfaces 2015, 7, 23932.
[12] Yang, F.; Xu, M.; Bao, S. J.; Wei, H.; Chai, H. Electrochim. Acta 2014, 137, 381.
[13] Fan, W.; Zhang, C.; Tjiu, W. W.; Pramoda, K. P.; He, C.; Liu, T. ACS Appl. Mater. Interfaces 2013, 5, 3382.
[14] Liu, Z.; Chen, W.; Fan, X.; Yu, J.; Zhao, Y. Chin. J. Chem. 2016, 34, 839.
[15] Fan, W., Xia, Y. Y.; Tjiu, W. W.; Pallathadka, P. K.; He, C.; Liu, T. J. Power Sources 2013, 243, 973.
[16] Luo, J.; Ma, Q.; Gu, H.; Zheng, Y.; Liu, X. Electrochim. Acta 2015, 173, 184.
[17] Trung, N. B.; Van Tam, T.; Kim, H. R.; Hur, S. H.; Kim, E. J.; Choi, W. M. Chem. Eng. J. 2014, 255, 89.
[18] Binks, B. P. Curr. Opin. Colloid Interface Sci. 2002, 7, 21.
[19] Wei, W.; Wang, T.; Luo, J.; Zhu, Y.; Gu, Y.; Liu, X. Colloids Surf., A 2015, 487, 58.
[20] McCoy, T. M.; Pottage, M. J.; Tabor, R. F. J. Phys. Chem. C 2014, 118, 4529.
[21] Hu, Z.; Marway, H. S.; Kasem, H.; Pelton, R.; Cranston, E. D. ACS Macro Lett. 2016, 5, 185.
[22] Kim, S. D.; Zhang, W. L.; Choi, H. J. J. Mater. Chem. C 2014, 2, 7541.
[23] Yin, G.; Zheng, Z.; Wang, H.; Du, Q.; Zhang, H. J. Colloid Interface Sci. 2013, 394, 192.
[24] Fei, X.; Xia, L.; Chen, M.; Wei, W.; Luo, J.; Liu, X. Materials 2016, 9, 731.
[25] Wan, W.; Zhao, Z.; Hughes, T. C.; Qian, B.; Peng, S.; Hao, X.; Qiu, J. Carbon 2015, 85, 16.
[26] Chen, X.; Eggers, P. K.; Slattery, A. D.; Ogden, S. G.; Raston, C. L. J. Colloid Interface Sci. 2014, 430, 174.
[27] Zhang, Y.; Zheng, X.; Wang, H.; Du, Q. J. Mater. Chem. A 2014, 2, 5304.
[28] Luo, J.; Jiang, S.; Liu, R.; Zhang, Y.; Liu, X. Electrochim. Acta 2013, 96, 103.
[29] Yang, J.; Shi, T.; Jin, W.; Zou, Y. Acta Chim. Sinica 2008, 66, 552. (杨家义, 史铁钧, 金维亚, 邹燕, 化学学报, 2008, 66, 552.)
[30] Zhu, Y.; Sun, J.; Yi, C.; Wei, W.; Liu, X. Soft Matter 2016, 12, 7577.
[31] Binks, B. P.; Lumsdon, S. O. Langmuir 2000, 16, 8622.
[32] Zheng, Z.; Zheng, X.; Wang, H.; Du, Q. ACS Appl. Mater. Interfaces 2013, 5, 7974.
[33] Zheng, X.; Zhang, Y.; Wang, H.; Du, Q. Macromolecules 2014, 47, 6847.
[34] Aveyard, R.; Binks, B. P.; Clint, J. H. Adv. Colloid Interface Sci. 2003, 100, 503.
[35] Yi, W.; Wu, H.; Wang, H.; Du, Q. Langmuir 2016, 32, 982.
[36] Luo, J.; Jiang, S.; Wu, Y.; Chen, M.; Liu, X. J. Polym. Sci., Part A:Polym. Chem. 2012, 50, 4888.
[37] Fan, W.; Zhang, C.; Tjiu, W. W.; Pramoda, K. P.; He, C.; Liu, T. ACS Appl. Mater. Interfaces 2013, 5, 3382.
[38] Zhou, H.; Sun, Y.; Li, G.; Chen, S.; Lu, Y. Polymer 2014, 55, 4459.
[39] Zang, X.; Li, X.; Zhu, M.; Li, X.; Zhen, Z.; He, Y.; Zhu, H. Na-noscale 2015, 7, 7318.
[40] Mu, B.; Zhang, W.; Wang, A. J. Nanopart. Res. 2014, 16, 1.
[41] Co?kun, E.; Zaragoza-Contreras, E. A.; Salavagione, H. J. Carbon 2012, 50, 2235.

Pickering乳液法制备聚苯胺-石墨烯空心微球

Polyaniline-graphene Hollow Spheres based on Graphene Stabilized Pickering Emulsions

PDF

Supporting Info.

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Xingyu Ma, Hui Sun, Jiang Li, Zhiyang Liu, Hongjun Zhou. “Continuous” Nitrogen Reduction Synthesis of Ammonia Based on Li-N₂ Battery System [J]. Acta Chimica Sinica, 2022, 80(7): 861-866.
[2]	Yao Zhai, Guoxiang Xin, Jiaqi Wang, Bangwen Zhang, Jinling Song, Xiaoxu Liu. Microwave-assisted Synthesis of rGO/CeO₂ Supercapacitor Electrode Materials with Excellent Electrochemical Properties [J]. Acta Chimica Sinica, 2021, 79(9): 1129-1137.
[3]	Xinxin Zhang, Rong Liu, Lei Wang, Honggang Fu. Study on the Construction and Properties of Bacterial Cellulose-Based Cathode for Flexible Zn-Ion Batteries [J]. Acta Chimica Sinica, 2021, 79(5): 670-677.
[4]	Hongyu Yuan, Minmin Xu, Jianlin Yao. SERS Studies on the Electrochemical and SPR Synergistic Catalytic Interfacial Reaction of 4-Chlorothiophenol [J]. Acta Chimica Sinica, 2021, 79(12): 1481-1485.
[5]	Liu Ji-Lin, Yu Kai, Zhang Hong, Jiang Jie. Progress in the Study of Electrochemical Reaction by Mass Spectrometric Ionization Sources [J]. Acta Chimica Sinica, 2020, 78(6): 504-515.
[6]	Yan Tingting, Xing Guolong, Ben Teng. One-step Strategy to Synthesize Porous Carbons by Carbonized Porous Organic Materials and Their Applications [J]. Acta Chim. Sinica, 2018, 76(5): 366-376.
[7]	Zhang Chengming, Pang Xin, Wang Yongzhao. Controllable Synthesis of One-dimensional Cryptomelane-type Manganese Dioxide and Its Electrochemical Performance [J]. Acta Chim. Sinica, 2018, 76(2): 133-137.
[8]	Yang Zheyao, Ma Wei, Ying Yilun, Long Yitao. Study on the Resolution of Single Silver Nanoparticles Electrochemical Behavior at Nanoelectrode [J]. Acta Chim. Sinica, 2017, 75(7): 671-674.
[9]	Dong Wei, Nie Mengsi, Lian Yongfu. Isolation and Electrochemical Property of Tb@C₈₂ Isomers [J]. Acta Chim. Sinica, 2017, 75(5): 453-456.
[10]	Yang Tao, Cui Yanan, Chen Huaiyin, Li Weihua. Controllable Preparation of Two Dimensional Metal- or Covalent Organic Frameworks for Chemical Sensing and Biosensing [J]. Acta Chim. Sinica, 2017, 75(4): 339-350.
[11]	Cui Xianghong, Chen Huaiyin, Yang Tao. Research Progress on the Preparation and Application of Nano-sized Molybdenum Disulfide [J]. Acta Chim. Sinica, 2016, 74(5): 392-400.
[12]	Xu Zhihui, Shen Liming, Wu Qiang, Sun Tao, Xu Yuyang, Li Danqin, Du Lingyu, Yang Lijun, Wang Xizhang, Hu Zheng. Oxygen Reduction Performance of the Nitrogen-Doped Carbon Materials Pyrolyzed from Polyaniline/Carbon Nanocage Composites [J]. Acta Chim. Sinica, 2015, 73(8): 793-798.
[13]	Han Ruobing, Lu Shan, Wang Yanjie, Zhang Xuehua, Wu Qiang, He Tao. Application of SO₄^- and I^- co-Doped Polyaniline Counter Electrode in Dye-sensitized Solar Cells [J]. Acta Chim. Sinica, 2015, 73(10): 1061-1068.
[14]	Lin Chao, Zhai Wei, Fan Louzhen, Li Xiaohong. DNA-Based Electrochemically Transduced and Resettable Keypad Lock [J]. Acta Chimica Sinica, 2014, 72(6): 709-712.
[15]	Zhang Qian, Wu Shuyao, Zhang Ling, Mao Hui, Liu Daliang, Liu Yang, Zeng Xiangqun, Song Ximing, Li Jinghong. Biocompatible Phospholipid Modified Graphene Nanocomposite for Direct Electrochemistry of Redox Enzyme [J]. Acta Chimica Sinica, 2014, 72(3): 388-394.