Chin. J. Org. Chem. ›› 2012, Vol. 32 ›› Issue (02): 284-293 .DOI: 10.6023/cjoc1104191 Previous Articles     Next Articles



薛福玲a, 李建晓a,b, 莫阳青a, 汪朝阳a, 陈庆华c   

  1. a 华南师范大学化学与环境学院 广州 510006;
    b 华南理工大学化学化工学院 广州 510640;
    c 北京师范大学化学学院 北京 100875
  • 收稿日期:2011-04-19 修回日期:2011-08-22 发布日期:2012-03-09
  • 通讯作者: 汪朝阳
  • 基金资助:

    国家自然科学基金(No. 20772035)、广东省自然科学基金(No. 5300082)和广东省高等学校人才引进专项资金(No. 粤财教[2011]431)资助项目.

Research Progress on Photochemical Reaction of α,β-Unsaturated Lactone

Xue Fulinga, Li Jianxiaoa,b, Mo Yangqinga, Wang Zhaoyanga, Chen Qinghuac   

  1. a School of Chemistry and Environment, South China Normal University, Guangzhou 510006;
    b School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640;
    c School of Chemistry, Beijing Normal University, Beijing 100875
  • Received:2011-04-19 Revised:2011-08-22 Published:2012-03-09
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 20772035), the Natural Science Foundation of Guangdong Province (No. 5300082) and the 3rd Talents Special Funds of Guangdong Higher Education (No. Guangdong-Finace-Education[2011]431).

Photochemical reaction of α,β-unsaturated lactone can be utilized in the synthesis of optical active products and natural products, such as nucleotide, ring alkaloids, terpenoids and steroids. Based on different reaction types, including photochemical 1,4-addition reaction, 1,4-addition-cyclization reaction, [2+2] cycloaddition reaction and complex photochemical cycloaddition reaction, the recent progresses in photochemical reactions of α,β-unsaturated lactones, especially 2(5H)-furanones, are reviewed.

Key words: α,β-unsaturated lactone, 2(5H)-furanone, photochemical 1,4-addition reaction, [2+2] cycloaddition reaction