Chin. J. Org. Chem. ›› 2012, Vol. ›› Issue (03): 627-631.DOI: 10.6023/cjoc1107202 Previous Articles     Next Articles



董建勋a,b, 石玉坤a, 胡晓静a, 冯晓燕b, 宋娟娟a, 丁真贞a, 刘向明a, 黄唯平a   

  1. a 南开大学化学系 天津 300071;
    b 中国平煤神马能源化工集团尼龙化工公司 平顶山 467013
  • 收稿日期:2011-07-20 修回日期:2011-10-25 发布日期:2012-03-24
  • 通讯作者: 黄唯平
  • 基金资助:

    国家自然科学基金(No. 21071086)资助项目.

Nickel(0)-Catalyzed Equilibrium Reaction of 3-Pentenenitrile

Dong Jianxuna,b, Shi Yukuna, Hu Xiaojinga, Feng Xiaoyanb, Song Juanjuana, Ding Zhenzhena   

  1. a College of Chemistry, Nankai University, Tianjin 300071;
    b China Pingmei Shenma Energy and Chemical Group Nylon Chemical Company, Pingdingshan 467013
  • Received:2011-07-20 Revised:2011-10-25 Published:2012-03-24
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21071086).

The equilibrium reaction of 3-pentenenitrile was carried out in the system containing Ni(0), P-ligand and anhydrous ZnCl2. The equilibrium state of 3-pentenenitrile was affected by factors such as reaction temperatures and different ligands, which were investigated. The FTIR-ATR was used to monitor the reaction process of 3-pentenenitrile turning into 2-methylglutaronitrile and adiponitrile in absence of HCN and the possible reaction mechanism was proposed.

Key words: zero-valent nickel, 3-pentenenitrile, 2-methylglutaronitrile, adiponitrile, reaction equilibrium