Selective Synthesis of Sulfoxides by Oxidation Using MoO3/Al2O3 as Catalyst

doi:10.6023/cjoc1105181

Chin. J. Org. Chem. ›› 2012, Vol. ›› Issue (03): 624-626.DOI: 10.6023/cjoc1105181 Previous Articles Next Articles

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MoO₃/Al₂O₃ 催化氧化选择性合成亚砜

孙莉, 杨振平, 郭罕奇, 裴文

浙江工业大学化学工程与材料学院杭州 310014

收稿日期:2011-05-18 修回日期:2011-10-19 发布日期:2012-03-24
通讯作者: 裴文 E-mail:peiwen58@zjut.edu.cn

Selective Synthesis of Sulfoxides by Oxidation Using MoO₃/Al₂O₃ as Catalyst

Sun Li, Yang Zhenping, Guo Hanqi, Pei Wen

College of Chemical Engineering and Materials, Zhejiang University of Technology, Hangzhou 310014

Received:2011-05-18 Revised:2011-10-19 Published:2012-03-24

MoO₃/Al₂O₃ solid base catalysts were prepared by impregnation method and the catalytic activity of MoO₃, Al₂O₃ and MoO₃/Al₂O₃ were investigated in the oxidation reaction of sulfoether to sulfoxide using H₂O₂ as oxidant. The result indicated that the conversion was 100% and no by-product produced when the catalyst of MoO₃/Al₂O₃ loaded 20% of MoO₃. Then, the intermediate of lansoprazole was oxidated by using the same method to get the corresponding lansoprazole in the yield of 80%. The catalyst could be used 6 times without deactivity.

Key words: MoO₃/Al₂O₃, sulfides, lansoprazole, oxidationg reaction

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Sun Li, Yang Zhenping, Guo Hanqi, Pei Wen. Selective Synthesis of Sulfoxides by Oxidation Using MoO₃/Al₂O₃ as Catalyst[J]. Chin. J. Org. Chem., 2012, (03): 624-626.

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MoO₃/Al₂O₃ 催化氧化选择性合成亚砜

Selective Synthesis of Sulfoxides by Oxidation Using MoO₃/Al₂O₃ as Catalyst

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MoO3/Al2O3 催化氧化选择性合成亚砜