Chin. J. Org. Chem. ›› 2014, Vol. 34 ›› Issue (12): 2448-2455.DOI: 10.6023/cjoc201406046 Previous Articles     Next Articles

REVIEW

乙烯基碳上的亲核取代反应

沈舒苏   

  1. 苏州科技学院分离净化材料与技术研发中心 苏州 215009
  • 收稿日期:2014-06-27 修回日期:2014-07-17 出版日期:2014-12-25 发布日期:2014-08-11

Nucleophilic Substitution Reactions at Vinylic Carbons

Shen Shusu   

  1. Center for Separation and Purification Materials & Technologies, Suzhou University of Science and Technology, Suzhou 215009
  • Received:2014-06-27 Revised:2014-07-17 Online:2014-12-25 Published:2014-08-11

The recently research progress in the nucleophilic substitution reactions at the sp2-carbons, mainly at the vinylic carbons is reviewed. The theoretical studies on the nucleophilic substitution reactions at the vinylic carbons, and their applications in organic synthesis, especially in the synthesis of heterocycle compounds, are illustrated. And, researches and applications of the nucleophilic substitution reactions at other unsaturated atoms like sp2 nitrogens are also discussed.

Key words: inylic carbon, sp2 carbon, nucleophilic substitution reaction, sp2 nitrogen