Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (4): 802-812.DOI: 10.6023/cjoc201410012 Previous Articles     Next Articles



罗海清, 张志鹏, 刘海东, 柳辉金   

  1. 赣南师范学院化学化工学院 赣州 341000
  • 收稿日期:2014-10-09 修回日期:2014-11-07 发布日期:2014-12-02
  • 通讯作者: 罗海清
  • 基金资助:

    江西省教育厅自然科学基金(Nos. GJJ14668, KJLD14080)及江西省普通本科高校中青年教师发展计划访问学者专项资金资助项目.

Advance of Organosilane in Transition-Metal-Catalyzed C—H Functionalization for C—C Bond Formation

Luo Haiqing, Zhang Zhipeng, Liu Haidong, Liu Huijin   

  1. Department of Chemistry & Chemical Engineering, Gannan Normal University, Ganzhou 341000
  • Received:2014-10-09 Revised:2014-11-07 Published:2014-12-02
  • Supported by:

    Project supported by the Natural Science Foundation of Jiangxi Provincial Education Department (Nos. GJJ14668, KJLD14080) and the Young Teacher Development Plan Visiting Scholar Special Funds of Jiangxi Ordinary Undergraduate Course Colleges and Universities.

As a kind of important organometallic reagents, organosilanes have been widely applied for C—C bond formation in organic synthesis. In this paper, recent development of trans-metal-catalyzed C—H functionalizations for C—C bond formation involving organosilanes is reviewed, in which Pd-catalyzed Hiyama coupling reactions is described as highlighted.

Key words: organosilane, C—H functionalizations, trans-metal catalyzed, C—C bond formation, Hiyama coupling reactions