Chin. J. Org. Chem. ›› 2015, Vol. 35 ›› Issue (5): 937-946.DOI: 10.6023/cjoc201501004 Previous Articles     Next Articles



陈静a,b, 曲红梅a, 彭静b, 陈超b   

  1. a 天津大学化工学院 系统生物工程教育部重点实验室 天津市生物制药工程重点实验室 天津 300072;
    b 清华大学化学系 生命有机磷化学及化学生物学教育部重点实验室 北京 100084
  • 收稿日期:2015-01-05 修回日期:2015-01-30 发布日期:2015-02-10
  • 通讯作者: 曲红梅, 陈超;
  • 基金资助:


Study of Electrophilic Cyclization Reactions Triggered by Diaryliodonium Salts

Chen Jinga,b, Qu Hongmeia, Peng Jingb, Chen Chaob   

  1. a Key Laboratory of Systems Bioengineering, Ministry of Education, Tianjin Key Laboratory of Biological and Pharma- ceutical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072;
    b Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology, Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084
  • Received:2015-01-05 Revised:2015-01-30 Published:2015-02-10
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos.21102099, 21102080, 21372138) and the Tsinghua University Initiative Scientific Research Program (No.2011Z02150).

Electrophilic cyclization reactions are one of the most useful strategies for the construction of various cyclic compounds and significant progress has been made in the electrophilic cyclizations triggered by diaryliodonium salts. In these new types of electrophilic cyclization reactions, diaryliodonium salts can not only act as arylation reagents to initiate arylation-cyclization reactions giving aryl-substituted compounds, but also to be involved in the benzocyclization to give benzocycles.

Key words: diaryliodonium salts, electrophilic cyclization, arylation-cyclization reactions, benzocyclization