Chin. J. Org. Chem. ›› 2016, Vol. 36 ›› Issue (7): 1555-1563.DOI: 10.6023/cjoc201601042 Previous Articles     Next Articles



黄家翩, 周豪, 陈知远   

  1. 江西师范大学化学化工学院 功能有机小分子教育部重点实验室 南昌 330022
  • 收稿日期:2016-01-29 修回日期:2016-02-28 发布日期:2016-03-18
  • 通讯作者: 陈知远
  • 基金资助:


Advances on the Metallocarbene Formation Reactions Based on Triazole Derivatives

Huang Jiapian, Zhou Hao, Chen Zhiyuan   

  1. Key Laboratory of Functional Small Organic Molecules, Ministry of Education, College of Chemistry & Chemical Engineering, Jiangxi Normal University, Nanchang 330022
  • Received:2016-01-29 Revised:2016-02-28 Published:2016-03-18
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21462022).

Carbenes are very useful key intermediates in organic synthesis, which generally display high reactivity in chemical transformations. Metallocarbenes can be regarded as metal stabilized organic carbenes. The research progress of the metallocarbene formation and the related reactions based on triazole compounds are reviewed in this work. The RhII-catalyzed metallocarbenes derived from N-sulfonyl-1,2,3-triazoles, as well as the subsequent insertion reactions into other reaction systems to generate new C-C or C-hetero bonds, are specially focused.

Key words: transition-metal-catalysis, metallocarbenes, triazole compounds, carbo and heterocyclic compounds