Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (4): 889-895.DOI: 10.6023/cjoc201611008 Previous Articles     Next Articles

ARTICLE

一种咪唑并吩嗪内酰胺反应型识别氰离子的荧光探针

李翔, 林奇, 曲文娟, 李乔, 程晓斌, 李文婷, 张有明, 姚虹, 魏太保   

  1. 西北师范大学化学化工学院 教育部生态环境相关材料重点实验室 甘肃省高分子材料重点实验室 兰州 730070
  • 收稿日期:2016-11-03 修回日期:2016-12-29 出版日期:2017-04-25 发布日期:2017-01-17
  • 通讯作者: 魏太保 E-mail:weitaibao@126.com
  • 基金资助:

    国家自然科学基金(Nos.21662031,21661028,21574104,21262032)资助项目.

A Novel Imidazophenazine Lactam Reaction Type Recognition Cyanide Ion Fluorescence Probe

Li Xiang, Lin Qi, Qu Wenjuan, Li Qiao, Chen Xiaobin, Li Wenting, Zhang Youming, Yao Hong, Wei Taibao   

  1. College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070
  • Received:2016-11-03 Revised:2016-12-29 Online:2017-04-25 Published:2017-01-17
  • Contact: 10.6023/cjoc201611008 E-mail:weitaibao@126.com
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21662031, 21661028, 21574104, 21262032).

A novel imidazophenazine lactam fluorescence chemosensor (S1) was designed, synthesized and characterized by 1H NMR, 13C NMR and HRMS techniques. Fluorescence spectra of S1 in dimethyl sulfoxide (DMSO) solution were measured. Its maximum emission wavelength was 524 nm. The DMSO solution of S1 has bright yellow fluorescence. Respectively, to the S1 solution add F-, Cl-, Br-, I-, AcO-, H2PO4-, HSO4-, ClO4-, and SCN-, the fluorescent color of the solution didn't change. Only the CN- addition, the fluorescent color of the S1 solution changed from yellow to orange-red, indicating that S1 has good specific selectivity for CN-. The results of anti-disturbance experiment demonstrated that S1 detect CN- without interference from other anions. By calculation, the linear of the fluorescence of the sensor for CN- is 9.96×10-7. This value is lower than the World Health Organization (WHO) provisions of the cyanide content of drinking water. Mechanism studies show that S1 is a fluorescence sensor by reactive recognition CN-. In addition, the application of sensor S1 supported on solid silica gel was used as a solid material to detecting solid NaCN and CN- in pure water.

Key words: phenazine derivative, fluorescence sensor, detecting anions