Chin. J. Org. Chem. ›› 2017, Vol. 37 ›› Issue (5): 1173-1180.DOI: 10.6023/cjoc201702042 Previous Articles     Next Articles

ARTICLE

铜催化烯酸和苯硫酚类化合物的氧硫化反应研究:合成硫化内酯类化合物

陈漫漫, 王力竞, 李玮   

  1. 河北大学化学与环境科学学院 保定 071002
  • 收稿日期:2017-02-27 修回日期:2017-04-01 出版日期:2017-05-25 发布日期:2017-04-18
  • 通讯作者: 王力竞,李玮 E-mail:wanglj0405@163.com;liweihebeilab@163.com
  • 基金资助:

    河北省自然科学基金重点(No.B2016201031)、河北省高等学校高层次人才科学研究(No.GCC2014014)、河北省自然科学基金青年(No.B2017201041)资助项目.

Copper-Catalyzed Oxysulfenylation of Alkenoic Acids with Benzenethiols: A Strategy to Construct Sulfenylated Lactones

Chen Manman, Wang Lijing, Li Wei   

  1. College of Chemistry & Environmental Science, Hebei University, Baoding 071002
  • Received:2017-02-27 Revised:2017-04-01 Online:2017-05-25 Published:2017-04-18
  • Contact: 10.6023/cjoc201702042 E-mail:wanglj0405@163.com;liweihebeilab@163.com
  • Supported by:

    Project supported by the Hebei Province Science, foundation for Key Program (No. B2016201031), the Hebei Province Higher School Science, foundation for High-level Personnel (No. GCC2014014), and the Hebei Province Science, foundation for Youths (No. B2017201041).

An efficient copper-catalyzed oxysulfenylation of alkenoic acids with benzenethiols via radical pathway was developed. The reactions are easy to be conducted under mild conditions and form a broad range of sulfenylated lactones.

Key words: copper-catalyzed, benzenethiols, radical reaction, oxysulfenylation, lactones