Chin. J. Org. Chem. ›› 2018, Vol. 38 ›› Issue (5): 1207-1213.DOI: 10.6023/cjoc201711036 Previous Articles     Next Articles



林雅玫, 易文斌   

  1. 南京理工大学化工学院 南京 210094
  • 收稿日期:2017-11-21 修回日期:2017-12-17 发布日期:2018-01-10
  • 通讯作者: 易文斌,
  • 基金资助:


A Route to Alkynyl Sulfides and Asymmetric Disulfides from Sodium Arylsulfiniate

Lin Yamei, Yi Wenbin   

  1. Chemical Engineering College, Nanjing University of Science & Technology, Nanjing 210094
  • Received:2017-11-21 Revised:2017-12-17 Published:2018-01-10
  • Contact: 10.6023/cjoc201711036
  • Supported by:

    Project supported by the National Natural Science Foundation of China (Nos. 21776138, 21476116), the Fundamental Research Funds for the Central Universities (No. 30916011102) and the Qing Lan and Six Talent Peaks in Jiangsu Province.

A new approach for the synthesis of alkynyl sulfides and asymmetric disulfides with odorless, easy-to-handle sodium arylsulfiniates as the sulfur source in I2/PPh3 aqueous system has been developed. Compared with reported approaches, this protocol provides several merits including simple procedures, free of transition-metal catalysts and organic solvent, and high yields.

Key words: reaction in water, sodium arylsulfiniate, alkynyl sulfide, asymmetric disulfide