Transition-Metal-Catalyzed Guanylation Reaction of Amines with Carbodiimides Constructing Guanidines

doi:10.6023/cjoc201801037

Abstract

Guanidine derivatives are an important class of nitrogen-containing organic compounds, which are widely used in various pharmaceuticals, agrochemicals, sweeteners, explosives, and so on. Although classical methods for the synthesis of guanidines are established, there are still many fatal shortcomings which need to be resolved. In recent years, it has been gradually turned to the direct catalytic guanylation reaction of amines with carbodiimides. In this paper, the recent progress in transition-metal-catalyzed guanylation reaction of amines with carbodiimides to construct acyclic or cyclic guanidines based on the catalytic reaction mechanism, reaction system, the scope of substrates, etc. is reviewed.

Key words: guanylation reaction, guanidines, amines, carbodiimides

Cite this article

Wang Lianjun, Chi Yue, Zhang Wenxiong, Xi Zhenfeng. Transition-Metal-Catalyzed Guanylation Reaction of Amines with Carbodiimides Constructing Guanidines[J]. Chin. J. Org. Chem., 2018, 38(6): 1341-1349.

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