Research Progress in Asymmetric Reactions of Imines Using Chiral Primary Amines as Organocatalysts

doi:10.6023/cjoc201908030

Chinese Journal of Organic Chemistry ›› 2020, Vol. 40 ›› Issue (6): 1514-1528.DOI: 10.6023/cjoc201908030 Previous Articles Next Articles

手性伯胺作为有机催化剂对亚胺的不对称反应研究进展

张永娜, 段慧欣, 汪游清

河南大学化学化工学院河南省多酸化学重点实验室河南省天然药物与免疫工程重点实验室河南开封 475004

收稿日期:2019-08-22 修回日期:2019-11-01 发布日期:2020-03-04
通讯作者: 张永娜, 汪游清 E-mail:zhangyongna@henu.edu.cn;wyouqing@hotmail.com
基金资助:
国家自然科学基金（No.U1404211）、河南省教育厅科学技术研究重点（No.14A150029）资助项目.

Research Progress in Asymmetric Reactions of Imines Using Chiral Primary Amines as Organocatalysts

Zhang Yongna, Duan Hui-Xin, Wang You-Qing

College of Chemistry and Chemical Engineering, Henan Key Laboratory of Polyoxometalate Chemistry, Provincial Key Laboratory of Natural Medicine and Immuno-Engineering, Henan University, Kaifeng, Henan 475004

Received:2019-08-22 Revised:2019-11-01 Published:2020-03-04
Supported by:
Project supported by the National Natural Science Foundation of China (No. U1404211), and the Key Scientific and Technological Research Projects of Henan Education Department (No. 14A150029).

Chiral primary amine is a kind of important small organic molecule catalyst in the field of asymmetric organocatalysis. Like secondary amine catalyst, primary amine can react with carbonyl compounds to form reactive intermediate of enamine or iminium to catalyze various asymmetric reactions, achieving excellent enantioselectivities. The catalytic asymmetric 1,2-addition to the electrophilic C=N double bond of imines (involving imine intermediates in the reaction process) is the most efficient way to obtain nitrogen-containing compounds bearing α-chiral center. In recent years, the highly enantioselective asymmetric reaction of imines by chiral primary amine catalysts has made some progress, so this topic is summarized and prospected.

Key words: chirality, primary amines, imines, asymmetric catalysis, organocatalysts

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Zhang Yongna, Duan Hui-Xin, Wang You-Qing. Research Progress in Asymmetric Reactions of Imines Using Chiral Primary Amines as Organocatalysts[J]. Chinese Journal of Organic Chemistry, 2020, 40(6): 1514-1528.

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手性伯胺作为有机催化剂对亚胺的不对称反应研究进展

Research Progress in Asymmetric Reactions of Imines Using Chiral Primary Amines as Organocatalysts

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